DEHYDROGENATION CATALYST WITH MINIMIZED AROMATIC PRODUCTION

    公开(公告)号:WO2021183372A1

    公开(公告)日:2021-09-16

    申请号:PCT/US2021/020994

    申请日:2021-03-05

    申请人: UOP LLC

    摘要: A catalyst composition and its use as a dehydrogenation catalyst to increase normal olefin selectivity and reduce undesirable aromatic selectivity. The reduction in aromatic production allows for the elimination of a unit to remove aromatic compounds. The catalyst has a layered composition comprising an inner core, an outer layer bonded to the inner core, the outer layer comprising one or more transition alumina with at least two diffraction angle peaks between 32.0 and 70.0 2?, wherein a first diffraction angle peak in that range is at 32.70.4 2?, a second diffraction angle peak is at 50.80.4 2?, and having a thickness of less than 100 microns and having uniformly dispersed thereon said platinum catalyst and at least one promoter metal and having a concentration of the platinum catalyst of from 0.00006 to 0.0005 gram of the platinum group metal on an elemental basis per meter square surface area of the outer layer.

    1,4-사이클로헥산디메탄올의 제조 방법

    公开(公告)号:WO2021132876A1

    公开(公告)日:2021-07-01

    申请号:PCT/KR2020/015572

    申请日:2020-11-09

    摘要: 본 발명은 1,4-사이클로헥산디메탄올(1,4-cyclohexanedimethanol, CHDM)의 제조 방법에 관한 것으로, 보다 상세하게는 반응물인 1,4-사이클로헥신디카르복실산(1,4-cyclohexane dicarboxylic acid, CHDA)의 함량 및/또는 반응 온도를 조절함으로써, 이성화 반응 단계를 포함하지 않아도 트랜스 이성질체의 비율이 높은 1,4-사이클로헥산디메탄올을 제조하는 방법에 관한 것이다.

    ハイドロフルオロオレフィンの製造方法

    公开(公告)号:WO2021044983A1

    公开(公告)日:2021-03-11

    申请号:PCT/JP2020/032710

    申请日:2020-08-28

    摘要: ハイドロフルオロオレフィンの製造方法は、パラジウム等からなる群より選択される少なくとも1種の第1金属と、第1金属とは異なる第2金属を含む金属間化合物の存在下で、式(I)又は式(II)で表される炭素数が8以下のクロロフルオロオレフィンを水素分子と反応させて、式(I)又は式(II)に含まれる塩素原子のうちの少なくともClで表された塩素原子が水素原子に置換されたハイドロフルオロオレフィンを得るものである。式(I)又は式(II)中、R1~R10は水素原子、フッ素原子、塩素原子又はフッ素原子若しくは塩素原子で置換されていてもよいアルキル基を示し、式(I)又は式(II)中に少なくとも1つのフッ素原子を含む。nは、0~5の整数を示す。

    A CATALYST COMPOSITION
    8.
    发明申请

    公开(公告)号:WO2020005161A1

    公开(公告)日:2020-01-02

    申请号:PCT/SG2019/050320

    申请日:2019-06-27

    发明人: LIU, Yan YAN, Wenjin

    摘要: The present invention relates a catalyst composition comprising metal oxides useful in a catalytic oxidative dehydrogenation of the short chains of alkene into its corresponding diene, in particular, the catalytic oxidative dehydrogenation of 1 -butene to 1,3-butadiene (BD). In a preferred embodiment, the catalyst is indium oxide (ln 2 O 3 ) supported on alumina (Al203) and optionally promoted by diphosphorus pentoxide (P 2 O 5 ) and/or platinum (Pt). The present invention also relates to a method for preparing the catalyst composition as defined herein.