公开(公告)号：WO2021247314A1

公开(公告)日：2021-12-09

申请号：PCT/US2021/034189

申请日：2021-05-26

申请人： SCION HOLDINGS LLC

发明人： KILLEBREW, Kyle ,  LANE, Samuel, Livingston

IPC分类号： B01J31/24 ,  C07C45/50 ,  C07C45/49 ,  B01J2231/321 ,  B01J2231/52 ,  B01J2531/822 ,  B01J31/185 ,  B01J31/20 ,  B01J31/2234 ,  B01J31/2404

摘要： A process for producing isomerized olefins, branched aldehydes, branched alcohols and branched surfactants through isomerization, hydroformylation, hydrogenation and surfactant forming reactions.

公开(公告)号：WO2021247516A8

公开(公告)日：2021-12-09

申请号：PCT/US2021/035169

申请日：2021-06-01

申请人： SCION HOLDINGS LLC

发明人： KILLEBREW, Kyle ,  LANE, Samuel, Livingston

IPC分类号： B01J29/70 ,  C07C11/02 ,  C07C5/25 ,  B01J2231/321 ,  B01J2531/822 ,  B01J31/1845 ,  B01J31/20 ,  B01J31/2234 ,  B01J31/2404 ,  C07C2523/46 ,  C07C2531/24 ,  C07C2531/26 ,  C07C29/141 ,  C07C45/50 ,  C07C45/505 ,  C07C5/2593 ,  C07C5/2794

摘要： A process for producing isomerized olefins, branched aldehydes and branched alcohols through isomerization, hydroformylation and hydrogenation.

公开(公告)号：WO2021198113A1

公开(公告)日：2021-10-07

申请号：PCT/EP2021/058040

申请日：2021-03-26

申请人： V. MANE FILS

发明人： GRASSET, Fabien ,  JAUNKY, Piotr

IPC分类号： B01J31/20 ,  B01J31/24 ,  B01J31/28 ,  C07C45/50 ,  B01J31/22 ,  C07C45/00 ,  C07C67/347 ,  B01J2231/321 ,  B01J2531/822 ,  B01J2531/827 ,  B01J2531/845 ,  B01J31/2234 ,  B01J31/2295 ,  B01J31/2404 ,  B01J31/2409 ,  C07C2601/14 ,  C07C2601/16

摘要： Described herein is a hydroformylation catalyst system and method useful for producing aldehydes from olefin substrates, without using carbon monoxide gas. The hydroformylation catalyst system includes a hydroformylation catalyst complex including a Group 9 metal complexed with a phosphine-based ligand; a syngas surrogate including formic acid and an anhydride compound, which forms carbon monoxide in situ; and hydrogen, which may derive from the syngas surrogate or not derived from the syngas surrogate. The method involves reacting the olefin substrate with a syngas surrogate in the presence of a hydroformylation catalyst complex, wherein the syngas surrogate forms carbon monoxide, and optionally hydrogen, in situ, and then isolating the aldehyde compound from a reaction mixture.