公开(公告)号：WO1996029750A1

公开(公告)日：1996-09-26

申请号：PCT/US1996003118

申请日：1996-03-06

Applicant: WILSON GREATBATCH LTD.

Inventor： WILSON GREATBATCH LTD. ,  GAN, Hong ,  TAKEUCHI, Esther, S.

IPC: H01M06/16

CPC classification number: H01M10/0567 ,  H01M6/164 ,  H01M6/168

Abstract: An alkali metal, solid cathode, nonaqueous electrochemical cell capable of delivering high current pulses, rapidly recovering its open circuit voltage and having high current capacity, is described. The stated benefits are realized by dissolving organic additives, preferably carbonate additives in the electrolyte. The carbonate additives have an O-X bond with a dissociation energy less than about 80 kcal/mol on either one or both sides of a carbonyl group wherein X is selected from the group consisting of C, O and N.

Abstract translation: 描述了能够传递高电流脉冲，快速恢复其开路电压并且具有高电流容量的碱金属，固体阴极，非水电化学电池。 所述的益处通过将有机添加剂，优选碳酸盐添加剂溶解在电解质中来实现。 碳酸酯添加剂在其中X选自C，O和N的羰基的一个或两侧上具有解离能小于约80kcal / mol的O-X键。

公开(公告)号：WO1996015562A1

公开(公告)日：1996-05-23

申请号：PCT/US1995012326

申请日：1995-11-14

Applicant: WILSON GREATBATCH LTD.

Inventor： WILSON GREATBATCH LTD. ,  TAKEUCHI, Esther, S. ,  WALSH, Karen, M.

IPC: H01M06/16

CPC classification number: H01M4/04 ,  H01M4/0404 ,  H01M4/0409 ,  H01M4/043 ,  H01M4/0435 ,  H01M4/48 ,  H01M6/16 ,  H01M6/166 ,  Y10T29/49108 ,  Y10T29/49112

Abstract: A high pulse power electrochemical cell comprising an alkali metal-aluminum alloy anode, a nickel anode current collector, a calendared mixed metal oxide cathode active material pressed onto a cathode current collector comprising aluminum and a nonaqueous electrolytic solution, is described. The electrolytic solution preferably comprises at least one ion-forming alkali metal salt of hexafluorophosphate with the alkali metal salt being similar to the alkali metal comprising the anode. Lithium is the preferred alkali metal. This cell system produces high current pulses and can be housed in a casing having a reduced volume with respect to conventional electrochemical systems. Additionally, the anode/electrolytic solution exhibits reduced voltage delay without comprising heat dissipation.

Abstract translation: 描述了一种包括碱金属 - 铝合金阳极，镍阳极集电器，压制在包括铝和非水电解液的阴极集电器上的压延复合金属氧化物正极活性材料的高脉冲电力电化学电池。 电解液优选包含至少一种六氟磷酸盐的离子形成碱金属盐，碱金属盐类似于包含阳极的碱金属。 锂是优选的碱金属。 该电池系统产生高电流脉冲，并且可以容纳在相对于常规电化学系统具有减小的体积的壳体中。 此外，阳极/电解液表现出降低的电压延迟，而不包括散热。

公开(公告)号：WO1998012762A1

公开(公告)日：1998-03-26

申请号：PCT/US1997016743

申请日：1997-09-19

Applicant: MOTOROLA INC.

Inventor： MOTOROLA INC. ,  GIES, Paul, J. ,  OLIVER, Manuel ,  ESCHBACH, Florence, O. ,  REICHERT, Veronica, R. ,  COALSON, Christen, E.

IPC: H01M06/16

CPC classification number: H01M10/0566 ,  H01M2/162 ,  H01M6/181 ,  H01M6/22 ,  H01M10/052 ,  H01M10/0565 ,  H01M10/26

Abstract: An electrolyte system (40) for use in connection with an electrochemical cell (10). The cell (10) includes a positive electrode (20) and a negative electrode (30) with the electrolyte system (40) disposed therebetween. The electrolyte system is a polymer gel electrolyte system including a liquid electrolyte species which may be either aqueous or non-aqueous and a polymer gel electrolyte support structure. The polymer gel electrolyte support structure includes at least a non woven first polymer and a second polymer which is adapted to absorb the electrolyte active species. The first polymer is a fibrous polymer to reduce swelling of the gel electrolyte in the presence of the electrolyte active species, and further to enhance mechanical integrity of the support structure.

Abstract translation: 一种用于与电化学电池（10）结合使用的电解质系统（40）。 电池（10）包括正极（20）和负极（30），其间设置有电解质体系（40）。 电解质体系是一种聚合物凝胶电解质体系，其包括可以是水性或非水性的液体电解质物质和聚合物凝胶电解质支持结构。 聚合物凝胶电解质支撑结构至少包括非织造第一聚合物和适于吸收电解质活性物质的第二聚合物。 第一聚合物是纤维聚合物，以在电解质活性物质的存在下减少凝胶电解质的溶胀，并进一步提高载体结构的机械完整性。

公开(公告)号：WO1996018215A1

公开(公告)日：1996-06-13

申请号：PCT/DK1995000502

申请日：1995-12-11

Applicant: DANIONICS A/S ,  WENDSJO, Åsa ,  CONSIGNY, Marine ,  YDE-ANDERSEN, Steen

Inventor： DANIONICS A/S

IPC: H01M06/16

CPC classification number: H01G9/022 ,  H01M6/181 ,  H01M10/0569 ,  Y02E60/13

Abstract: A new non-aqueous electrolyte system for use in batteries, capacitors or electrochromic displays, and consisting essentially of an alkali or ammonium salt, a solvent mixture, and optionally a polymer is disclosesd. The new electrolyte system is characterised in that the solvent mixture comprises a mixture of ethylene carbonate (EC) and gamma -valerolactone ( gamma -VL), optionally containing one or more additional solvents selected from other organic carbonates, other lactones, esters and glymes, said system optionnaly being confined in a separator. The electrolyte system can be applied in a broad voltage range, has a conductivity higher than 10 S/cm at room temperature, and shows a high stability against reduction. The improved stability towards reduction is mirrored in a cycling efficiency which is superior to the cycling efficiency of known non-aqueous electrolyte systems.

Abstract translation: 公开了一种用于电池，电容器或电致变色显示器，并且基本上由碱或铵盐，溶剂混合物和任选的聚合物组成的新的非水电解质体系。 新的电解质系统的特征在于溶剂混合物包含碳酸亚乙酯（EC）和γ-戊内酯（γ-VL）的混合物，任选地含有一种或多种另外的选自其它有机碳酸酯，其它内酯，酯和甘氨酸的溶剂， 所述系统选项被限制在分隔符中。 电解质体系可以在宽的电压范围内使用，导电率在室温下高于10 -3 S / cm，显示出高的抗还原稳定性。 改进的降低稳定性反映在循环效率上，其优于已知非水电解质体系的循环效率。

公开(公告)号：WO1997044842A1

公开(公告)日：1997-11-27

申请号：PCT/US1997009053

申请日：1997-05-22

Applicant: SRI INTERNATIONAL

Inventor： SRI INTERNATIONAL ,  NARANG, Subhash, C. ,  VENTURA, Susanna, C. ,  ZHAO, Ming ,  SMEDLEY, Stuart ,  KOOLPE, Gary ,  DOUGHERTY, Brian, J.

IPC: H01M06/16

CPC classification number: H01M10/0567 ,  H01M6/162 ,  H01M6/164 ,  H01M6/168 ,  H01M10/0566 ,  H01M10/0569 ,  H01M2300/0034

Abstract: Novel fire-retardant electrolyte compositions are provided. These compositions comprise a lithium salt dissolved in a fire-retardant solvent selected from the group consisting of phosphates, phospholanes, cyclophosphazenes, silanes, fluorinated carbonates, fluorinated polyethers and mixtures thereof. The electrolyte composition optionally contains a CO2-generating compound. Also provided are fire-retardant batteries and fire-retardant conductive films formulated with such compositions, as well as methods of manufacturing such films.

Abstract translation: 提供了新的阻燃电解质组合物。 这些组合物包含溶解在选自磷酸盐，磷脂，环磷腈，硅烷，氟化碳酸酯，氟化聚醚及其混合物的阻燃溶剂中的锂盐。 电解质组合物任选地含有产生CO 2的化合物。 还提供了用这种组合物配制的阻燃电池和阻燃导电膜，以及制造这种膜的方法。

公开(公告)号：WO1992002966A1

公开(公告)日：1992-02-20

申请号：PCT/US1991005262

申请日：1991-07-25

Applicant: COVALENT ASSOCIATES INCORPORATED

Inventor： COVALENT ASSOCIATES INCORPORATED ,  DOMINEY, Lawrence, A.

IPC: H01M06/16

CPC classification number: H01M10/052 ,  C07C49/16 ,  C07C49/167 ,  C07C49/185 ,  C07C205/45 ,  C07C317/04 ,  H01M6/166 ,  H01M10/0565

Abstract: Salts for use in nonaqueous electrolytes, and electrolytes and electrochemical generators including such materials. An exemplary compound for use as an electrolyte in an electrochemical cell has formula (I) wherein Mn+ is an ion of Li, Na, K, Ca, Mg, Zn, or Al; each of the moieties Y, Y', and Y'', are (a) or (b); the groups R and R' are separate halogenated alkyl groups of 1-4 carbon atoms, respectively or are joined together to constitute a unitary halogenated alkylene radical of from 2-4 carbon atoms linking Y and Y' and forming a ring structure which includes R, R', Y, Y', and the carbon atom to which Y and Y' are attached; the group R'' is an alkyl or haloalkyl radical of 1-4 carbon atoms or a halogenated phenyl group; n is an integer of 1-3 depending on the identity of the metal M; and metal ion Mn+ is an ion of Li, Na, Ca, Mg, Zn or Al when each of the Y-R, Y'-R', and Y''-R'' groups is SO¿2?CF3. In another exemplary compound, the -Y''-R'' group is replaced by Z, which is an electron-withdrawing substituent selected from the group consisting of -C(O)H, -NO2, -CN, -F, and perfluorinated alkyls and aryls containing no more than 8 carbons.

公开(公告)号：WO1985002497A1

公开(公告)日：1985-06-06

申请号：PCT/US1984001601

申请日：1984-10-09

Applicant: AMERICAN TELEPHONE & TELEGRAPH COMPANY

Inventor： AMERICAN TELEPHONE & TELEGRAPH COMPANY ,  VYAS, Brijesh

IPC: H01M06/16

CPC classification number: H01M10/26

Abstract: The addition of certain polymer compounds such as polybenzimidazole increases the capacity and cycle life of cadmium electrodes in nickel-cadmium batteries.

公开(公告)号：WO1982001443A1

公开(公告)日：1982-04-29

申请号：PCT/US1981000985

申请日：1981-07-23

Applicant: GTE LABORATORIES INC

Inventor： GTE LABORATORIES INC ,  PELED EMANUEL ,  LOMBARDI ANTHONY

IPC: H01M06/16

CPC classification number: H01M6/14

Abstract: An Electrochemical cell having an oxidizable anode material (22), specifically lithium, a cathode current collector (24), and an electrolytic solution in contact with the anode material (22) and the cathode current collector (24). The solution comprises a solvent of a reducible liquid cathode material, specifically thionyl chloride, and an electrolyte solvent, specifically lithium tetrachloroaluminate, dissolved therein. The solute is present in an amount to produce in excess of 75% of its room temperature saturation concentration in the solvent.

Abstract translation: 具有可氧化负极材料（22），特别是锂，阴极集电体（24）和与阳极材料（22）和阴极集电体（24）接触的电解液的电化学电池。 该溶液包括溶解在其中的可还原液体阴极材料的溶剂，特别是亚硫酰氯，以及电解质溶剂，特别是四氯铝酸锂。 溶质的存在量超过溶剂中室温饱和浓度的75％。

公开(公告)号：WO1995031835A1

公开(公告)日：1995-11-23

申请号：PCT/US1995005881

申请日：1995-05-10

Applicant: BELL COMMUNICATIONS RESEARCH, INC.

Inventor： BELL COMMUNICATIONS RESEARCH, INC. ,  GOZDZ, Antoni, S. ,  SCHMUTZ, Caroline, N. ,  TARASCON, Jean-Marie ,  WARREN, Paul, C.

IPC: H01M06/16

CPC classification number: C08J9/28 ,  C08J2327/16 ,  H01M2/1653 ,  H01M6/181 ,  H01M10/052 ,  H01M10/0565

Abstract: A polymeric film useful as an interelectrode separator or electrolyte member in electrolytic devices, such as rechargeable batteries, comprises a copolymer of vinylidene fluoride and hexafluoropropylene, a medium to high-boiling plasticizer, and a finely divided inorganic filler which has been subjected to actinic radiation or thermal energy to cause crosslinking thereof in the presence of a crosslinking agent selected from the group consisting of an acrylate ester, di- or triallyl ester and a di- or triglycidyl ether.

Abstract translation: 用作电解装置（例如可再充电电池）中的电极间隔离物或电解质构件的聚合物膜包括偏二氟乙烯和六氟丙烯的共聚物，中至高沸点增塑剂和经过光化辐射的细碎无机填料 或热能在交联剂存在下引起交联，所述交联剂选自丙烯酸酯，二或三烯丙酯和二 - 或三缩水甘油醚。

公开(公告)号：WO1994024711A1

公开(公告)日：1994-10-27

申请号：PCT/US1994001417

申请日：1994-02-09

Applicant: VALENCE TECHNOLOGY, INC.

Inventor： VALENCE TECHNOLOGY, INC. ,  CHALONER-GILL, Benjamin

IPC: H01M06/16

CPC classification number: H01M6/181 ,  C08K3/30 ,  C08K3/32 ,  Y10T29/49108 ,  C08L31/00

Abstract: This invention is directed to novel allyl carbonates and to solid electrolytes containing a solid matrix having incorporated therein allyl carbonates. The solid matrix is used in an electrolytic cell.

Abstract translation: 本发明涉及新型碳酸烯丙酯和含有其中加入碳酸烯丙酯的固体基质的固体电解质。 固体基质用于电解槽。