ALKOXYLATED UNSATURATED FATTY ACIDS AND USES THEREOF
    2.
    发明申请
    ALKOXYLATED UNSATURATED FATTY ACIDS AND USES THEREOF 审中-公开
    烷氧基化不饱和脂肪酸及其用途

    公开(公告)号:WO2017136264A1

    公开(公告)日:2017-08-10

    申请号:PCT/US2017/015589

    申请日:2017-01-30

    Abstract: Alkoxylated fatty acids are disclosed herein, as well as methods of making and using such compounds. In some embodiments, the alkoxylated fatty acids are formed from monomers derived from natural oils. In some embodiments, the alkoxylated fatty acids are used as surfactants for making synthetic latex by emulsion polymerization. In some other embodiments, the alkoxylated fatty acids are used as surfactants for making synthetic rubber, such as styrene-butadiene rubber. In some other embodiments, the alkoxylated fatty acids are used as surfactants in a composition for treatment of gas or oil wells, for cleaning applications, for use in various laundry-related applications, for use in personal care compositions, or for use as solvents for coating applications, such as reactive and non-reactive waterborne coating applications.

    Abstract translation: 本文公开了烷氧基化脂肪酸,以及制备和使用这些化合物的方法。 在一些实施方案中,烷氧基化脂肪酸由衍生自天然油的单体形成。 在一些实施方案中,烷氧基化脂肪酸用作通过乳液聚合制备合成胶乳的表面活性剂。 在一些其他实施方案中,烷氧基化脂肪酸用作制造合成橡胶例如苯乙烯 - 丁二烯橡胶的表面活性剂。 在一些其他实施方案中,烷氧基化脂肪酸在用于处理气井或油井的组合物中用作表面活性剂,用于清洁应用,用于各种洗衣相关应用,用于个人护理组合物中或用作 涂料应用,如反应性和非反应性水性涂料应用。

    PREPARATION OF A SORBATE ESTER
    3.
    发明申请
    PREPARATION OF A SORBATE ESTER 审中-公开
    SORBATE ESTER的制备

    公开(公告)号:WO2016061756A1

    公开(公告)日:2016-04-28

    申请号:PCT/CN2014/089153

    申请日:2014-10-22

    CPC classification number: C07C67/26 C07C67/58 C07C69/587

    Abstract: The present invention is a process for preparing a sorbate ester comprising the steps of: a) contacting together in a reaction vessel a first organic solvent, sorbic acid, a catalytic amount of TiCl 4 , an anti-oxidant, and an alkylene oxide under conditions sufficient to form a mixture of the sorbate ester and residual water-soluble impurities; then b) separating the sorbate ester from the residual water-soluble impurities by washing. Sorbate esters can be prepared in an efficient and cost-effective manner by the process of the present invention.

    Abstract translation: 本发明是一种制备山梨酸酯的方法,包括以下步骤:a)在反应容器中使第一有机溶剂,山梨酸,催化量的TiCl 4,抗氧化剂和烯化氧在足够的条件下接触在一起 形成山梨酸酯和残留的水溶性杂质的混合物; 然后b)通过洗涤将山梨酸酯与残留的水溶性杂质分离。 山梨酸酯可以通过本发明的方法以有效和成本有效的方式制备。

    PROCESS AND CATALYST FOR OBTAINING FATTY ACID METHYL ESTERS
    5.
    发明申请
    PROCESS AND CATALYST FOR OBTAINING FATTY ACID METHYL ESTERS 审中-公开
    用于获得脂肪酸甲酯的方法和催化剂

    公开(公告)号:WO2015069129A1

    公开(公告)日:2015-05-14

    申请号:PCT/RO2013/000019

    申请日:2013-11-20

    Abstract: The invention refers to a process and catalyst for obtaining fatty acid methyl esters, by the chemical processing of fats with content of free fatty acids, in order to be used as diesel biofuel, also referred to as biodiesel, intermediates for synthetic biofuels for aviation, or environmental-friendly solvents. The process according to the invention consists of treating the fats with methanol and with super-acid solid catalyst S0427Ti02-La203j at temperatures of 68±2°C, the water resulting din esterification reaction of the fatty acids is separated from methanol in a rectification column and is removed, and methanol is recirculated, until the acidity index of the reaction mass drops under 2 mg KOH/g, the super-acid solid catalyst is removed by filtration, and the filtrate is treated in the next step with a heterogeneous alkaline catalyst, at temperatures of 67±2°C, for 60-90 minute, the catalyst is removed by filtration or centrifugation, glycerine is separated from the methyl esters of fatty acids by decantation or centrifugation, and is then treated with the heterogeneous alkaline catalyst separated before, at temperatures of 67±2°C, for 60-90 minute, the catalyst is removed by filtration or centrifugation, and excess methanol is removed by distillation, first at atmospheric pressure and then under vacuum, glycerine is separated from the methyl esters of fatty acids by decantation or centrifugation, which is finally filtered through an inorganic filtering layer. The heterogeneous alkaline catalyst according to the invention has the molecular formula: CH2,464- 2.5350o,428-o,528No.o3i-o.o43Clo.o3 i-o.o43Cao. io5-o.i29Sio.o64-o.o73, and the process for obtaining it consists of treating the calcium oxide with methanol with a molar ratio of 1 :4, at a temperature of 65°C for 60 minutes, treating the mixture with glycerine with a molar ratio of 1 : 1 to the calcium oxide, at temperatures of 65-70°C for 60 minutes, methanol is removed by distillation from the reaction mass, which is treated with a solvent, with triethanolamine with a molar ratio of 1 :2 to the calcium oxide, and with trialkylchlorosilane with a molar ratio of 1 :2 to the calcium oxide, at ambient temperature, for 60-120 minutes, the resulting suspension is filtered, and the solvent is removed by drying.

    Abstract translation: 本发明涉及用于获得脂肪酸甲酯的方法和催化剂,通过化学处理游离脂肪酸含量的脂肪,以用作柴油生物燃料(也称为生物柴油),用于航空的合成生物燃料的中间体, 或环保溶剂。 根据本发明的方法包括用甲醇处理脂肪和在68±2℃的温度下用过酸固体催化剂S0427Ti02-La203j处理,将得到的脂肪酸二酯酯化反应的水与精馏塔中的甲醇分离 并除去甲醇,直到反应物质的酸度指数下降到2mg KOH / g以下,过滤除去过酸固体催化剂,并在下一步中用不均匀的碱性催化剂处理滤液 ,在67±2℃的温度下60-90分钟,通过过滤或离心除去催化剂,通过倾析或离心将甘油与脂肪酸的甲酯分离,然后用分离的非均相碱性催化剂处理 之前,在67±2℃的温度下60-90分钟,通过过滤或离心除去催化剂,并通过蒸馏除去过量的甲醇,首先在大气压 然后在真空下,通过倾析或离心将甘油与脂肪酸的甲酯分离,最终通过无机过滤层过滤。 根据本发明的非均相碱性催化剂具有分子式:CH2,464-2.5350o,428-o,528No.o3i-o.o43Clo.o3 i-o.o43Cao。 io5-o.i29Sio.o64-o.o73,其获得方法包括用摩尔比为1:4的甲醇处理氧化钙,在65℃的温度下处理60分钟,用 甘油与氧化钙的摩尔比为1:1,在65-70℃的温度下搅拌60分钟,通过蒸馏从用溶剂处理的反应物质中除去甲醇,其中三乙醇胺的摩尔比为 1:2与氧化钙的摩尔比为1:2的三烷基氯硅烷与氧化钙在环境温度下反应60-120分钟,过滤得到的悬浮液,通过干燥除去溶剂。

    METHOD FOR PRODUCING BIODIESEL
    7.
    发明申请
    METHOD FOR PRODUCING BIODIESEL 审中-公开
    生物体生产方法

    公开(公告)号:WO2013032090A9

    公开(公告)日:2014-06-05

    申请号:PCT/KR2012002268

    申请日:2012-03-28

    Abstract: The present invention relates to a method for producing biodiesel comprising a step of generating fatty acid alkyl ester and glycerol by a transesterification of animal and vegetable oils and fats and fatty acid alcohols in the presence of porous materials. The method is characterized by a high response speed and high FAME conversion, and can be performed in a consecutive process. Further, according to the method, a high-purity fatty acid alkyl ester and glycol can be produced irrespective of the content of free fatty acids (FFAs). Further, since the method does not use a catalyst, the total processing time and cost can be reduced, and the method is environmentally friendly.

    Abstract translation: 本发明涉及一种生产生物柴油的方法,其包括在多孔材料存在下通过动植物油和脂肪酸醇的酯交换产生脂肪酸烷基酯和甘油的步骤。 该方法的特征在于高响应速度和高FAME转换,并且可以在连续的过程中执行。 此外,根据该方法,可以生产高纯度脂肪酸烷基酯和二醇,而与游离脂肪酸(FFA)的含量无关。 此外,由于该方法不使用催化剂,因此可以减少总的处理时间和成本,并且该方法是环境友好的。

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