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发明公开
CN101781254A 一类具有氟两相性质双子离子液体以及利用该离子液体制得的催化剂及其用途 无效 - 撤回

一类具有氟两相性质双子离子液体以及利用该离子液体制得的催化剂及其用途
摘要：
本发明公开了一类具有氟两相性质双子离子液体，分子式为：[(R1N2C3H3)2R]2+·[2X-]，结构由通式(I)表示，其中R1代表氢或C1～C8的烷基；R表示亚乙氧基单元，选自-(CH2CH2O)qCH2CH2-，其中q＝6～250，是由聚乙二醇400-10000形成的；X代表HBF4，HPF6、HNO3、卤代氢。在该类具有氟两相性质双子离子液体中加入钯、铑或镍金属催化剂配位即制得催化剂，可用于HECK，C-C耦合反应、异构化反应。该离子液体不易挥发，利用该离子液体制得的催化剂用于HECK，C-C耦合反应、异构化反应，催化效率高，可重复使用。 式(I)
摘要（英）：

The invention discloses gemini ionic liquid with fluorous biphasic property. The molecular formula of the ionic liquid is [(R1N2C3H3)2R]2+.[2X-]. The structure of the ionic liquid is shown as the general formula (I) in the specification, wherein R1 represents hydrogen or C1-C8 alkyl; R represents ethylidene oxyl element, is selected from-(CH2CH2O)qCH2CH2- and is formed by polyethylene glycol 400-10000, and q is 6-250; and X represents HBF4, HPF6, HNO3 or halogenated hydrogen. A catalyst can be prepared immediately after adding palladium, rhodium or nickel catalyst into the gemini ionic liquid with fluorous biphasic property for coordination, and can be used in HECK reaction, C-C coupling reaction and isomerization reaction. The ionic liquid is not easy to volatilize, and the catalyst prepared by utilizing the ionic liquid is used in HECK reaction, C-C coupling reaction and isomerization reaction, has high catalytic efficiency and can be reused.

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