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发明授权
CN103987714B 金属卟啉配位化合物、其制造方法及由其构成的二氧化碳固定化催化剂、以及环状碳酸酯的制造方法 失效 - 权利终止

金属卟啉配位化合物、其制造方法及由其构成的二氧化碳固定化催化剂、以及环状碳酸酯的制造方法
摘要：
本发明提供一种下述通式(1)所示的金属卟啉配位化合物。(式(1)中，M为金属。A1～A4分别独立地为下述通式(2)所示的取代基。)(式(2)中，D为碳原子数1～20的2价有机基团。E+为碳原子数3～60的季铵基或季鏻基。X为卤素原子。)由此，在用作二氧化碳固定化催化剂时，显示高催化活性，环境负荷小，而且可容易地合成。
摘要（英）：

There is provided a metalloporphyrin complex represented by general formula (1): wherein M is a metal; A 1 to A 4 are independently of each other a substituent represented by general formula (2): €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ-D-E X - €ƒ€ƒ€ƒ€ƒ€ƒ(2) wherein D is a divalent organic group having 1 to 20 carbon atoms; E + is a quaternary ammonium group or quaternary phosphonium group having 3 to 60 carbon atoms; and X is a halogen atom. There is thus provided a metalloporphyrin complex which, when used as a carbon dioxide fixation catalyst, exhibits high catalytic activity, has a small environmental burden and can be easily synthesized.

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