The invention provides an organic electroluminescence compound with triarylnaphthalene. The compound has relatively good thermal stability, high light emission efficiency and high light emission purity, can be used for manufacturing organic electroluminescence devices and can be applied to fields such as organic solar batteries, organic film transistors or organic photoreceptors. The invention further provides an organic electroluminescence device which comprises an anode, a cathode and organic layers, wherein the organic layers comprise at least one of a light emitting layer, a hole injection layer, a hole transport layer, a hole barrier layer, an electron injection layer and an electron transport layer; at least one of the organic layers comprises the compound of a structural formula I as shown in the specification.