发明公开
EP0446537A1 Process for preparing lower alkyl-halides
失效
烯丙基卤化物(Verfahren zur Herstellung von niedrigen)烷基卤化物。
- 专利标题: Process for preparing lower alkyl-halides
- 专利标题(中): 烯丙基卤化物(Verfahren zur Herstellung von niedrigen)烷基卤化物。
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申请号: EP90400667.3申请日: 1990-03-13
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公开(公告)号: EP0446537A1公开(公告)日: 1991-09-18
- 发明人: Segall, Jeane , Shorr, Leonard M.
- 申请人: Bromine Compounds Ltd.
- 申请人地址: Makleff House P.O.B. 180 Beer-Sheva 84101 IL
- 专利权人: Bromine Compounds Ltd.
- 当前专利权人: Bromine Compounds Ltd.
- 当前专利权人地址: Makleff House P.O.B. 180 Beer-Sheva 84101 IL
- 代理机构: Gillard, Marie-Louise
- 主分类号: C07C19/02
- IPC分类号: C07C19/02 ; C07C17/16
摘要:
A process for preparing lower alkyl-halides from the reaction of HX and the corresponding lower alcohol, wherein X represents a halogen atom, comprises continuously feeding HX and a lower alcohol to a reactor maintaining the instantaneous molar ratio of HX to the alcohol greater than 3, and continuously distilling off lower alkyl-halide and water from the reactor, continuously separating the lower alkyl-halide and water and recycling part of the said water to the distillation column to abate HX distillation from the reactor. High acid concentrations and temperatures are maintained to obtain high yields and rapid conversion of alkanols.
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