发明公开
EP0717740A1 PHOTOCHROME VERBINDUNGEN, VERFAHREN UND ZWISCHENPRODUKTE ZU DEREN HESTELLUNG UND DEREN VERWENDUNG
失效
PHOTO铬化合物及其运营部门中间体和它们的使用方法
- 专利标题: PHOTOCHROME VERBINDUNGEN, VERFAHREN UND ZWISCHENPRODUKTE ZU DEREN HESTELLUNG UND DEREN VERWENDUNG
- 专利标题(英): Photochromic compounds, methods and intermediates for producing them and their use
- 专利标题(中): PHOTO铬化合物及其运营部门中间体和它们的使用方法
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申请号: EP94922875.0申请日: 1994-09-03
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公开(公告)号: EP0717740A1公开(公告)日: 1996-06-26
- 发明人: LEHN, Jean-Marie , KAWAI, Stephen , GILAT, Sylvain
- 申请人: CIBA-GEIGY AG
- 申请人地址: Klybeckstrasse 141 CH-4002 Basel CH
- 专利权人: CIBA-GEIGY AG
- 当前专利权人: CIBA-GEIGY AG
- 当前专利权人地址: Klybeckstrasse 141 CH-4002 Basel CH
- 优先权: CH19930002721 19930910
- 国际公布: WO1995007275 19950316
- 主分类号: G02B5
- IPC分类号: G02B5 ; C07D207 ; C07D233 ; C07D277 ; C07D333 ; C07D401 ; C07D403 ; C07D409 ; C07D417 ; C07D491 ; C07D495 ; C07F5 ; C09K9 ; G03C1 ; G11B7
摘要:
The invention concerns compounds of formula (I ou II), or their salts, in which the radicals have for instance the following meaning: R1 and R2 are each hydrogen, C1-C8 alkyl, cyano or -NO2 or together are (-CF2-)m, -CF(OCH3)-CF2-CF(OCH3)-, -CF[NH2]-CF2-CF[-NH2]-, -C(=O)-O-C(=O)-, -C(=NH)-NH-C(=NH)- or -C(=O)-NH-C(=O)-; R3 and R4 are methyl; A1 and A2, independently of each other, are formyl, an acetal or thioacetal radical, phenyl, pyridiniumyl, pyridyl or other heterocyclic groups, or groups of formula (III or IV); X1 and X2 are S, O or N(R18); Y1 and Y2 are =CH- or =N-; R5 and R6 are hydrogen, halogen, -B(OH)2, C1-C8 alkyl, C1-C8 alkylthio, cyano, nitro, -N(R17)2, -C(=O)-R19, -C≡CH, phenyl or pyridyl, and R9 is a bridging group containing up to three hetero-atoms. The invention also concerns the preparation of these compounds for example by reacting alkenes with 3-haloheterocycles in the presence of a strong base; intermediates of formula (VIb) used to produce these compounds, where A2, R4, X2 and Y2 are as above, where A2 cannot be -CHO, but additionally -B(OH)2 and -CH=NR26; compositions containing these compounds, and the use of the compounds or compositions described above as dyes, colour indicators, photo-switches or data stores.
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