发明公开
- 专利标题: HEAVY AROMATICS PROCESSING
- 专利标题(中): 治疗重芳烃
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申请号: EP96907037.0申请日: 1996-02-09
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公开(公告)号: EP0808299A1公开(公告)日: 1997-11-26
- 发明人: BUCHANAN, John, Scott , CHESTER, Arthur, Warren , FUNG, Shiu, Lun, Anthony , KINN, Timothy, Frederick , MIZRAHI, Sadi
- 申请人: MOBIL OIL CORPORATION
- 申请人地址: 3225 Gallows Road Fairfax, Virginia 22037-0001 US
- 专利权人: MOBIL OIL CORPORATION
- 当前专利权人: MOBIL OIL CORPORATION
- 当前专利权人地址: 3225 Gallows Road Fairfax, Virginia 22037-0001 US
- 代理机构: Kador & Partner
- 优先权: US19950386892 19950210
- 国际公布: WO1996024568 19960815
- 主分类号: C07C2
- IPC分类号: C07C2 ; B01J29 ; C07C5 ; C07C6 ; C07C15 ; C10G35 ; C10G45 ; C10G47 ; C10G49
摘要:
A heavy aromatics feed is converted to lighter aromatics products, such as benzene, toluene and xylenes by contacting a C9+ aromatics fraction and benzene and/or toluene over a catalyst comprising a zeolite, such as ZSM-12, and hydrogenation component, preferably platinum. The catalyst, complete with hydrogenation component, is treated to reduce aromatics loss. Treatment includes exposure to steam and/or sulfur after incorporation of the hydrogenation component. For additional stability and aromatics retention the steamed and/or sulfur treated catalyst is sulfided by cofeeding a source of sulfur. A low hydrogen partial pressure is preferably employed to assist in aromatics retention.
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