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公开(公告)号:EP0808299B1
公开(公告)日:2001-03-28
申请号:EP96907037.4
申请日:1996-02-09
发明人: BUCHANAN, John, Scott , CHESTER, Arthur, Warren , FUNG, Shiu, Lun, Anthony , KINN, Timothy, Frederick , MIZRAHI, Sadi
IPC分类号: C07C2/64 , C07C5/52 , C07C15/067 , C07C15/08
CPC分类号: C10G47/16 , B01J29/7415 , B01J29/7469 , B01J29/7476 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C07C6/126 , C07C2529/74 , C10G35/095 , Y02P20/52 , Y10S585/906
摘要: A heavy aromatics feed is converted to lighter aromatics products, such as benzene, toluene and xylenes by contacting a C9+ aromatics fraction and benzene and/or toluene over a catalyst comprising a zeolite, such as ZSM-12, and hydrogenation component, preferably platinum. The catalyst, complete with hydrogenation component, is treated to reduce aromatics loss. Treatment includes exposure to steam and/or sulfur after incorporation of the hydrogenation component. For additional stability and aromatics retention the steamed and/or sulfur treated catalyst is sulfided by cofeeding a source of sulfur. A low hydrogen partial pressure is preferably employed to assist in aromatics retention.
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公开(公告)号:EP1137739A1
公开(公告)日:2001-10-04
申请号:EP00904469.4
申请日:2000-01-21
发明人: CHESTER, Arthur, Warren , GREEN, Larry, Arthur , DHINGRA, Sandeep, Singh , MASON, Timothy , TIMKEN, Hye, Kyung, Cho
IPC分类号: C10G11/05
CPC分类号: C07C6/126 , B01J29/04 , B01J29/70 , C01B39/085 , C01B39/48 , C07C2/66 , C07C4/18 , C07C5/2708 , C07C6/123 , C07C2529/70 , C07C15/02 , C07C15/00
摘要: A process for catalytic cracking of a hydrocarbon feedstock feeds to produce an enhanced yield butylenes and isobutane comprises contacting the feedstock with a catalyst composition comprising MCM-68. The MCM-68 may be used as the primary cracking catalyst or may be used as an additive component in conjunction with a conventional cracking catalyst, such as a large pore molecular sieve having a pore size greater than 7 Angstrom.
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公开(公告)号:EP1066260A1
公开(公告)日:2001-01-10
申请号:EP98964189.9
申请日:1998-12-21
IPC分类号: C07D213/06 , C07D213/08 , C07D213/14
CPC分类号: C07C211/00 , C07B61/00 , C07D213/06 , C07D213/08 , C07D213/10 , C07D213/14
摘要: A process for producing pyridine or picoline compounds, comprises the steps: a) reacting a reactant feedstream comprising ammonia and at least one C1-5 carbonyl reactant in the presence of a molecular sieve catalyst to produce a primary product stream comprising pyridine or picoline products and polyalkylpyridines; b) isolating from the primary product stream a product fraction comprising pyridine or picoline products, and a polyalkylpyridine fraction comprising polyalkylpyridines; and c) contacting the polyalkylpyridine fraction with a molecular sieve catalyst to produce a secondary product stream comprising pyridine or picoline products, preferably by recycling the polyalkylpyridine fraction back to step (a).
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公开(公告)号:EP0914308A1
公开(公告)日:1999-05-12
申请号:EP97931077.0
申请日:1997-06-09
发明人: CHESTER, Arthur, Warren , FUNG, Shiu, Lun, Anthony , KRESGE, Charles, Theodore , ROTH, Wieslaw, Jerzy
CPC分类号: B01J29/80 , B01J29/084 , B01J29/70 , B01J29/7038 , B01J2229/12 , B01J2229/42 , C01B33/38 , C07C2/58 , C07C2/66 , C07C2529/70 , C10G11/05
摘要: A layered composition of matter, MCM-56, has an X-ray diffraction including the lines listed in Table (II) and has been selectively modified so that the ratio of the number of active acid sites at its external surface to the number of internal active acid sites is greater than that of the unmodified material. When used as an additive to a large pore zeolite catalyst in the catalytic cracking of a petroleum feedstock, the modified MCM-56 gives an improved gasoline yield/octane relationship, an improved coke selectivity and a higher combined gasoline and potential alkylate yield than an identical catalyst containing unmodified MCM-56.
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公开(公告)号:EP0808299A1
公开(公告)日:1997-11-26
申请号:EP96907037.0
申请日:1996-02-09
发明人: BUCHANAN, John, Scott , CHESTER, Arthur, Warren , FUNG, Shiu, Lun, Anthony , KINN, Timothy, Frederick , MIZRAHI, Sadi
CPC分类号: C10G47/16 , B01J29/7415 , B01J29/7469 , B01J29/7476 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C07C6/126 , C07C2529/74 , C10G35/095 , Y02P20/52 , Y10S585/906
摘要: A heavy aromatics feed is converted to lighter aromatics products, such as benzene, toluene and xylenes by contacting a C9+ aromatics fraction and benzene and/or toluene over a catalyst comprising a zeolite, such as ZSM-12, and hydrogenation component, preferably platinum. The catalyst, complete with hydrogenation component, is treated to reduce aromatics loss. Treatment includes exposure to steam and/or sulfur after incorporation of the hydrogenation component. For additional stability and aromatics retention the steamed and/or sulfur treated catalyst is sulfided by cofeeding a source of sulfur. A low hydrogen partial pressure is preferably employed to assist in aromatics retention.
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公开(公告)号:EP0979144A1
公开(公告)日:2000-02-16
申请号:EP98906636.0
申请日:1998-02-23
IPC分类号: B01J29/06
CPC分类号: B01J29/005 , B01J29/0308 , B01J29/041 , B01J29/084 , B01J2229/42
摘要: A composition for passivating metal contaminants in catalytic cracking of hydrocarbons includes a non-layered, ultra-large pore crystalline material with at least one peak at a position greater than about 18 Angstrom Units d-spacing with a relative intensity of 100, and a benzene adsorption capacity of greater than about 15 grams benzene per 100 grams anhydrous crystal at 50 torr and 25 °C, and a metal passivator incorporated within the crystalline material. A method for passivating contaminating metals uses the composition during catalytic cracking as an additive or as a component of the catalyst.
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公开(公告)号:EP0823936A1
公开(公告)日:1998-02-18
申请号:EP96912807.0
申请日:1996-04-15
发明人: CHESTER, Arthur, Warren , KRESGE, Charles, Theodore , QUINONES, Augusto, Rodolfo , VALYOCSIK, Ernest, W.
摘要: A process is provided for converting feedstock hydrocarbon compounds to product hydrocarbon compounds having a lower molecular weight than feedstock hydrocarbon compounds over a catalyst composition which comprises MCM-58 or a mixture of MCM-58 and another, e.g., intermediate- or large-pore, molecular sieve component. An embodiment of the present invention comprises an improved catalytic cracking process to produce high octane gasoline and lower molecular weight olefins, e.g. propylene.
摘要翻译: 提供了一种用于将原料烃化合物转化成具有比原料烃化合物低的分子量的产物烃化合物的方法,所述催化剂组合物包含MCM-58或MCM-58与另一种例如中孔或大孔的混合物, 分子筛组分。 本发明的一个实施方案包括改进的催化裂化工艺以生产高辛烷值汽油和低分子量烯烃, 丙烯。
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