发明公开
- 专利标题: OLEFIN POLYMERS PREPARED WITH SUBSTITUTED INDENYL CONTAINING METAL COMPLEXES
- 专利标题(中): 聚烯烃与咪唑类茚金属络合物MADE
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申请号: EP98918908.9申请日: 1998-05-01
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公开(公告)号: EP0977787A1公开(公告)日: 2000-02-09
- 发明人: KALE, Lawrence, T. , VANDERLENDE, Daniel, D. , NICKIAS, Peter, N. , PATTON, Jasson, T. , STEVENS, James, C. , PARIKH, Deepak, R. , MANGOLD, Debra, J.
- 申请人: THE DOW CHEMICAL COMPANY
- 申请人地址: 2030 Dow Center Midland, Michigan 48674 US
- 专利权人: THE DOW CHEMICAL COMPANY
- 当前专利权人: THE DOW CHEMICAL COMPANY
- 当前专利权人地址: 2030 Dow Center Midland, Michigan 48674 US
- 代理机构: Ottevangers, Sietse Ulbe
- 优先权: US45348P 19970501; US45410P 19970501
- 国际公布: WO9849211 19981105
- 主分类号: C08F210/16
- IPC分类号: C08F210/16 ; C08F4/645
摘要:
The subject invention is directed to an olefin polymer produced by polymerizing at least one α-olefin in the presence of a Group 4 metal complex comprising an indenyl group substituted in the 2 or 3 position with at least one group selected from hydrocarbyl, perfluoro-substituted hydrocarbyl, silyl, germyl and mixtures thereof, said indenyl group further being covalently bonded to the metal by means of a divalent ligand group, wherein the divalent ligand comprises nitrogen or phosphorus having an aliphatic or alicyclic hydrocarby group covalently bonded thereto via a primary or secondary carbon. Preferred olefin polymers of the invention will be characterized as having a high molecular weight, narrow molecular weight distribution, high vinyl content, and a bimodal DSC melting curve or a deconvoluted ATREF or GPC curve which shows at least two distinct narrow peaks. The olefin polymer will have utiliity in a variety of applications, including but not limited to films, fibers, foams, molded parts, and as components of formulations such as adhesives, sealants, coatings, caulks, and asphalt.
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