发明公开
EP1335943A1 ACRYLATPOLYMERISATE AUF BASIS VON TERT.BUTYLACRYLAT UND/ODER TERT.-BUTYLMETHACRYLAT
有权
丙烯酸酯聚合物基于叔丁酯和/或甲基丙烯酸叔丁酯
- 专利标题: ACRYLATPOLYMERISATE AUF BASIS VON TERT.BUTYLACRYLAT UND/ODER TERT.-BUTYLMETHACRYLAT
- 专利标题(英): Acrylate polymers based on tert-butyl acrylate and/or tert-butyl methacrylate
- 专利标题(中): 丙烯酸酯聚合物基于叔丁酯和/或甲基丙烯酸叔丁酯
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申请号: EP01993637.6申请日: 2001-11-09
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公开(公告)号: EP1335943A1公开(公告)日: 2003-08-20
- 发明人: DAUSCH, Wilma, M. , ZEITZ, Katrin , SCHNEIDER, Tanja , ANGEL, Maximilian , DE POTZOLLI, Bernd , WOOD, Claudia
- 申请人: BASF AKTIENGESELLSCHAFT
- 申请人地址: 67056 Ludwigshafen DE
- 专利权人: BASF AKTIENGESELLSCHAFT
- 当前专利权人: BASF AKTIENGESELLSCHAFT
- 当前专利权人地址: 67056 Ludwigshafen DE
- 优先权: DE10055776 20001110
- 国际公布: WO02038638 20020516
- 主分类号: C08F220/18
- IPC分类号: C08F220/18 ; A61K7/06
摘要:
The invention relates to acrylate polymers comprising a K-value ranging from 10 to 60, which can be obtained by the radical polymerization of: 30 to 99 wt. % of tert-butyl acrylate and/or tert-butyl methacrylate designated as monomer A; 1 to 28 wt. % of acrylic acid and/or methacrylic acid designated as monomer B, and; 0 to 60 wt. % of a radically copolymerizable monomer or of a radically copolymerizable monomer mixture designated as monomer C, whereby at least one of monomers C yields a homopolymer with a glass-transition temperature lower than 30 °C, with the provision that the wt. %'s total 100. The radical polymerization is carried out in the presence of alkane thiols with a C chain length of C 14 to C 22. The invention also relates to acrylate polymers comprising a K-value ranging from 10 to 60, which can be obtained by the radical polymerization of: 30 to 99 wt. % of tert-butyl acrylate and/or tert-butyl methacrylate designated as monomer A; 1 to 28 wt. % of acrylic acid and/or methacrylic acid designated as monomer B, and; 0 to 60 wt. % of a radically copolymerizable monomer or of a radically copolymerizable monomer mixture designated as monomer C, whereby at least one of monomers C yields a homopolymer with a glass-transition temperature lower than 30 °C, with the provision that the wt. %'s total 100. The radical polymerization is carried out in the presence of alkane thiols with a C chain length of C 10 to C 22 followed by a hydrogen peroxide treatment. The invention also relates to the use of these acrylate polymers as film formers as well as to their use in cosmetic preparations.
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