发明授权
EP1646664B1 VERFAHREN ZUR HERSTELLUNG VON POLYVINYLALKOHOL-FREIEN, WÄSSRI GEN POLYMERDISPERSIONEN
有权
工艺制造聚乙烯醇水-FREE,WÄSSRIGEN聚合物分散体
- 专利标题: VERFAHREN ZUR HERSTELLUNG VON POLYVINYLALKOHOL-FREIEN, WÄSSRI GEN POLYMERDISPERSIONEN
- 专利标题(英): Method for the production of polyvinyl alcohol-free, aqueous polymer dispersions
- 专利标题(中): 工艺制造聚乙烯醇水-FREE,WÄSSRIGEN聚合物分散体
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申请号: EP04740794.5申请日: 2004-07-08
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公开(公告)号: EP1646664B1公开(公告)日: 2006-10-04
- 发明人: STARK, Kurt , HÖGL, Christian
- 申请人: Wacker Polymer Systems GmbH & Co. KG
- 申请人地址: Johannes-Hess-Strasse 24 84489 Burghausen DE
- 专利权人: Wacker Polymer Systems GmbH & Co. KG
- 当前专利权人: Wacker Polymer Systems GmbH & Co. KG
- 当前专利权人地址: Johannes-Hess-Strasse 24 84489 Burghausen DE
- 代理机构: Schuderer, Michael
- 优先权: DE10332621 20030717
- 国际公布: WO2005014675 20050217
- 主分类号: C08F218/08
- IPC分类号: C08F218/08 ; C08F2/30 ; C08F283/00
摘要:
The invention relates to a method for the production of polyvinyl alcohol-free, aqueous polymer dispersions by means of radical polymerisation of one or several ethylenically unsaturated monomers in an aqueous medium. The invention is characterised in that polymerisation occurs in the presence of a stabilisator system, containing a) one or several polyalkylene oxides having identical or different structural units from the group comprising -(CH2)n-O- wherein n = 2 to 4, -CH2-CHR-O- wherein R = C1- to C15- alkyl, -CH2-CHOR'-O- wherein R' = H, C1- to C15-alkyl, containing, in the case of alkylene oxide-mixed polymerisates, alkylene oxide units with static distribution, and with identical or different end groups R'' from the group comprising an H group, OH group, alkyl group and O-alkyl group. The alkyl radical can be branched or unbranched and is a C1- to C20 alkyl radical, and b) one or several compounds of the group comprising condensation products of alkylene oxides having 2 to 4 C atoms with linear or branched alkyl alcohol having 6 to 24 C- atoms, alkyl phenols, or linear and branched alkyl monocarboxylic acids having 6 to 24 C atoms, and block copolymers made of at least two different alkylene oxides having 2 to 4 C atoms.
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