Technical solutions are described for an emissions control system for a motor vehicle including an internal combustion engine. The emissions control system includes a selective catalytic reduction (SCR) device, an NOx sensor, and a controller for ammonia slip detection. The ammonia slip detection includes comparing an NOx measurement from the NOx sensor with a predicted NOx value. In response to the NOx measurement exceeding the predicted NOx value by a threshold value, the threshold value being calibrated to a first predetermined value, the threshold value is calibrated to a second predetermined value, a timer is initiated to a predetermined duration, and during the predetermined duration of the timer, in response to a second NOx measurement from the NOx sensor exceeding the predicted NOx value by the threshold value set to the second predetermined value, a reductant dosing rate of the SCR device is adapted according to the second predetermined value.