A power delivery controller applied to a power converter includes a voltage compensation circuit and a comparator. The voltage compensation circuit is used for generating a compensation reference voltage, receiving a response signal through a universal serial bus type-C cable, and generating a response voltage when an electronic device coupled to the universal serial bus type-C cable generates the response signal corresponding to a Biphase Mark Coding (BMC) signal, wherein the response voltage and the compensation reference voltage have information relative to an internal resistor of the universal serial bus type-C cable. The comparator is used for generating a comparison signal according to the response voltage and the compensation reference voltage, wherein the power converter transmits power to the electronic device according to a specification corresponding to universal serial bus power delivery (USB-PD) after the comparator generates the comparison signal.