Various layer separation states are generated by the combination of a polyamide acid ester and a polyamide acid and a long residual image characteristic cannot be further improved merely by combining them. A liquid crystal display device comprises a substrate, a liquid crystal layer, and an orientation film placed between the substrate and the liquid crystal layer. The orientation film comprises a polyimide precursor having two or more components. In the polyimide precursor, an octanol-water partition coefficient is defined as log P and the difference in log P (Δ log P) between the two components having most distant log Ps is set so as to fall within a prescribed range.