Invention Grant
- Patent Title: Polymeric ion traps for suppressing or minimizing transition metal ions and dendrite formation or growth in lithium-ion batteries
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Application No.: US15644422Application Date: 2017-07-07
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Publication No.: US10581119B2Publication Date: 2020-03-03
- Inventor: Ion C. Halalay , Zicheng Li , Timothy J. Fuller , Bob R. Powell, Jr.
- Applicant: GM Global Technology Operations LLC
- Applicant Address: US MI Detroit
- Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLC
- Current Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLC
- Current Assignee Address: US MI Detroit
- Agency: Harness, Dickey & Pierce, P.L.C.
- Main IPC: H01M10/42
- IPC: H01M10/42 ; H01M10/0567 ; H01M10/052 ; H01M4/13 ; B01J39/04 ; B01J39/18 ; C08J5/22 ; H01M10/0525 ; H01M10/0568 ; H01M4/587 ; H01M2/16 ; H01M4/36 ; H01M4/62

Abstract:
Electrochemical cells that cycle lithium ions and methods for suppressing or minimizing dendrite formation are provided. The electrochemical cells include a positive electrode, a negative electrode, and a separator disposed therebetween. At least one transition metal ion-trapping moiety, including one or more polymers functionalized with one or more trapping groups, may be included within the electrochemical cell as a coating, pore filler, substitute pendant group, or binder. The one or more trapping groups may be selected from the group consisting of: crown ethers, siderophores, bactins, ortho-phenanthroline, iminodiacetic acid dilithium salt, oxalates malonates, fumarates, succinates, itaconates, phosphonates, and combinations thereof, and may bind to metal ions found within the electrochemical cell to minimize or suppress formation of dendrite protrusions on the negative electrode.
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