A control method of monitoring deterioration of a battery of a vehicle, may include determining, by a controller, whether an entry condition of allowing an entry to a deterioration monitoring mode of the battery is satisfied; setting, by the controller, a deterioration monitoring condition when the entry condition of allowing the entry to the deterioration monitoring mode of the battery is satisfied; performing, by the controller, charging of the battery after the setting of the deterioration monitoring condition is completed; and stopping, by the controller, the charging and determining a deterioration rate of the battery when a first state of charge (SOC) value of the battery is greater than a predetermined first reference value as a result of the performing the charging.