A method of forming a self-cleaning film system includes ink jet printing a composition onto a substrate. The composition includes an oleophobic material and a photocatalytic material. The method further includes curing the composition to form a self-cleaning film disposed on the substrate and thereby form the self-cleaning film system. The self-cleaning film includes a first plurality of regions including the photocatalytic material and disposed within the oleophobic material such that each of the first plurality of regions abuts and is surrounded by the oleophobic material.