Invention Grant
- Patent Title: Dimethyl-silyl-bridged-1-substituted-2-indenyl metallocene complexes for olefin polymerization
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Application No.: US16500645Application Date: 2018-04-04
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Publication No.: US11155659B2Publication Date: 2021-10-26
- Inventor: Nicolaas Hendrika Friederichs , Antonio Vittoria , Roberta Cipullo , Vincenzo Busico , Ilya Borisov , Alexander Voskoboynikov , Bogdan A. Guzeev , Dmitry Y. Mladentsev , Mikhail I. Sharikov , Dmitry Uborsky , Hendriksen Coen
- Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
- Applicant Address: NL Bergen op Zoom
- Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
- Current Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
- Current Assignee Address: NL Bergen op Zoom
- Agency: Cantor Colburn LLP
- Priority: EP17164678 20170404
- International Application: PCT/EP2018/058625 WO 20180404
- International Announcement: WO2018/185173 WO 20181011
- Main IPC: C07F17/00
- IPC: C07F17/00 ; C08F4/64 ; C08F4/76 ; C08F210/16 ; C08F4/6392

Abstract:
The invention relates to a metallocene complex according to formula A, wherein R1-R10 are independently selected from H, C1-C10 alkyl, C7-C20 Aralkyl groups, and C1-C10 alkoxy groups; wherein R11 is selected from methyl, ethyl, propyl, isopropyl, butyl, phenyl; wherein R1 and R2, R3 and R4, R4 and R5, R5 and R6, R7 and R8, R8 and R9, and/or R9 and R10 can be connected to form a ringstructure; wherein R0 is selected from a C1-C10 alkyl group or an aryl group wherein M is selected from Ti, Zr and Hf, X is an anionic ligand to M, z is the number of X groups and equals the valence of M minus 2. The invention further relates to a catalyst for preparing polyolefins, a process for polymerizing olefins and to polymers prepared by said catalyst system.
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