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公开(公告)号：US11472895B2
公开(公告)日：2022-10-18
申请号：US17267663
申请日：2019-08-29
发明人： Coen Hendriksen , Nicolaas Hendrika Friederichs , Jaiprakash Brijlal Sainani , Anamitra Chatterjee , Vyatcheslav Izmer , Dmitry Kononovich , Alexander Voskoboynikov , Vincenzo Busico , Roberta Cipullo , Antonio Vittoria , Oleg V. Samsonov
IPC分类号： C08F210/16 , C08F4/6592 , C08F4/659
摘要： The present invention provides a compound according to formula (I): (I) wherein: •R2 is abridging moiety containing at least one sp2 hybridised carbon atom; •each R4, R4′, R7 and R7′ are hydrogen or moieties comprising 1-10 carbon atoms, wherein each R4, R4′, R7 and R7′ are the same; •each R5, R5′, R6 and R6′ are moieties comprising 1-10 carbon atoms, wherein each R5, R5′, R6 and R6′ are the same; and •Z is a moiety selected from ZrX2, HfX2, or TiX2, wherein X is selected from the group of halogens, alkyls, aryls and aralkyls. Such compound allows for the preparation of catalyst systems that provide improved olefin reactivity, such as ethylene reactivity, increased molecular weight in olefin polymerisation, such as increased Mw in ethylene polymerisation, and increased comonomer incorporation in copolymerisation reactions of olefins, such as in copolymerisation reactions of ethylene with 1-hexene.
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2.发明授权公开(公告)号：US11155659B2
公开(公告)日：2021-10-26
申请号：US16500645
申请日：2018-04-04
发明人： Nicolaas Hendrika Friederichs , Antonio Vittoria , Roberta Cipullo , Vincenzo Busico , Ilya Borisov , Alexander Voskoboynikov , Bogdan A. Guzeev , Dmitry Y. Mladentsev , Mikhail I. Sharikov , Dmitry Uborsky , Hendriksen Coen
IPC分类号： C07F17/00 , C08F4/64 , C08F4/76 , C08F210/16 , C08F4/6392
摘要： The invention relates to a metallocene complex according to formula A, wherein R1-R10 are independently selected from H, C1-C10 alkyl, C7-C20 Aralkyl groups, and C1-C10 alkoxy groups; wherein R11 is selected from methyl, ethyl, propyl, isopropyl, butyl, phenyl; wherein R1 and R2, R3 and R4, R4 and R5, R5 and R6, R7 and R8, R8 and R9, and/or R9 and R10 can be connected to form a ringstructure; wherein R0 is selected from a C1-C10 alkyl group or an aryl group wherein M is selected from Ti, Zr and Hf, X is an anionic ligand to M, z is the number of X groups and equals the valence of M minus 2. The invention further relates to a catalyst for preparing polyolefins, a process for polymerizing olefins and to polymers prepared by said catalyst system.
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3.发明授权公开(公告)号：US11691998B2
公开(公告)日：2023-07-04
申请号：US17985254
申请日：2022-11-11
发明人： Coen Hendriksen , Nicolaas Hendrika Friederichs , Alexander Z. Voskoboynikov , Antonio Vittoria , Vincenzo Busico , Roberta Cipullo , Dmitry Y. Mladentsev , Bogdan A. Guzeev , Dmitry V. Uborsky
IPC分类号： C07F17/00 , C08F4/6592 , C08F210/16 , C08F4/76 , C08F10/02
CPC分类号： C07F17/00 , C08F4/65927 , C08F4/76 , C08F10/02 , C08F210/16
摘要： The invention relates to a metallocene complex according to formula (I), (I) wherein R1 and R2 are independently selected from H, an alkyl or an aryl group, wherein R3 is a C1-C10 alkyl group, wherein R′ is selected from H, an alkyl group, an aryl group and wherein different R′ substituents can be connected to form a ring structure and wherein B is a 1,2 phenylene bridging moiety, which can be optionally substituted, wherein Mt is selected from Ti, Zr and Hf, X is an anionic ligand, z is the number of X groups and equals the valence of Mt minus 2. The invention also relates to a catalyst comprising the reaction product of the metallocene complex and a cocatalyst. Further the invention relates to a (co)polymerisation process of olefinic monomers.
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公开(公告)号：US20200270292A1
公开(公告)日：2020-08-27
申请号：US16067863
申请日：2017-01-02
发明人： Shaneesh Vadake Kulangara , Nicolaas Hendrika Friederichs , Anton Ginzburg , Alexander Voskoboynikov , Vyatcheslav Izmer , Dmitry Kononovich , Oleg Samsonov , Antonio Vittoria , Vincenzo Busico , Roberta Cipullo , Ninad Ghavale , Nitin Nandurkar , Ilya Borisov , Bogdan Guzeev , Dmitry Uborsky
IPC分类号： C07F17/00 , C08F4/6592
摘要： The invention relates to a metallocene complex according to formula I or II wherein M is a metal selected from lanthanides or transition metals from group 3, 4, 5 or 6 of the Periodic System of the Elements, Q is an anionic ligand to M, k is the number of Q groups and equals the valence of M minus 2, R is a divalent bridging group, R1, R2, R3 and R4 are each independently chosen from the group consisting of hydrogen (H); a halogen atom; a silyl, alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl group; and R5, R6, R7 and R8 are each independently chosen from the group consisting of hydrogen (H); a halogen atom; a silyl, alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl group; or two adjacent radicals R5 and R6, R6 and R7, and R7 and Ware connected with each other in a hydrocarbon ring system. The invention also relates to a catalyst comprising the metallocene complex, to a process for making polyolefms and to the use of the polyolefins for making articles.
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公开(公告)号：US11427608B2
公开(公告)日：2022-08-30
申请号：US16500658
申请日：2018-04-04
发明人： Nicolaas Hendrika Friederichs , Antonio Vittoria , Roberta Cipullo , Vincenzo Busico , Ilya Borisov , Bogdan A. Guzeev , Dmitry Y. Mladentsev , Mikhail I. Sharikov , Dmitry Uborsky , Alexander Voskoboynikov , Hendriksen Coen
IPC分类号： C07F17/00 , C08F4/6592 , C08F210/16 , C08F4/659 , C08F10/00
摘要： The invention relates to a metallocene complex according to formula (A): wherein R1 is selected from C1-C10 alkyl, C6-C20 aryl, C7-C20 aralkyl groups, and C1-C10 alkoxy groups, wherein R2 is selected from H, C1-C10 alkyl; wherein R3-R6, R10 are independently selected from H, C1-C10 alkyl, C6-C10 aryl, and wherein R3 and R4, R4 and R5, or R5 and R6 can be connected to form a ringstructure; wherein M is selected from Ti, Zr and Hf, X is an anionic ligand to M, z is the number of X groups and equals the valence of M minus 2, and wherein each R7 independently is selected from C1-C6 alkyl or aryl groups. The invention also relates to a catalyst comprising the reaction product of the metallocene complex and a cocatalyst. Further the invention relates to a (co)polymerization process of olefinic monomers.
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公开(公告)号：US11352386B2
公开(公告)日：2022-06-07
申请号：US16500663
申请日：2018-04-04
发明人： Nicolaas Hendrika Friederichs , Antonio Vittoria , Roberta Cipullo , Vincenzo Busico , Ilya Borisov , Bogdan A. Guzeev , Dmitry Y. Mladentsev , Mikhail I. Sharikov , Dmitry Uborsky , Alexander Voskoboynikov , Hendriksen Coen
IPC分类号： C07F17/00 , C08F210/16 , C08F4/6592
摘要： The invention relates to a metallocene complex according to formula (I), wherein R1 is selected from C2-C10 alkyl, preferably C3-C10 alkyl, C6-C20 aryl, C7-C20 aralkyl groups, wherein R2 is selected from H, C1-C10 alkyl, and wherein R3, R4, R5 and R6 are independently selected from H, C1-C10 alkyl, C6-C20 aryl, or C7-C20 aralkyl groups and wherein R3 and R4, R4 and R5, or R5 and R6 can be connected to form a ring structure wherein M is selected from Ti, Zr and Hf, X is an anionic ligand to M. The invention also relates to a catalyst comprising the reaction product of the metallocene complex and a cocatalyst. Further the invention relates to a (co)polymerization process of olefinic monomers.
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公开(公告)号：US11040995B2
公开(公告)日：2021-06-22
申请号：US16067863
申请日：2017-01-02
发明人： Shaneesh Vadake Kulangara , Nicolaas Hendrika Friederichs , Anton Ginzburg , Alexander Voskoboynikov , Vyatcheslav Izmer , Dmitry Kononovich , Oleg Samsonov , Antonio Vittoria , Vincenzo Busico , Roberta Cipullo , Ninad Ghavale , Nitin Nandurkar , Ilya Borisov , Bogdan Guzeev , Dmitry Uborsky
IPC分类号： C07F17/00 , C08F210/16 , C08F4/6592
摘要： The invention relates to a metallocene complex according to formula I or II wherein M is a metal selected from lanthanides or transition metals from group 3, 4, 5 or 6 of the Periodic System of the Elements, Q is an anionic ligand to M, k is the number of Q groups and equals the valence of M minus 2, R is a divalent bridging group, R1, R2, R3 and R4 are each independently chosen from the group consisting of hydrogen (H); a halogen atom; a silyl, alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl group; and R5, R6, R7 and R8 are each independently chosen from the group consisting of hydrogen (H); a halogen atom; a silyl, alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl group; or two adjacent radicals R5 and R6, R6 and R7, and R7 and R8 are connected with each other in a hydrocarbon ring system. The invention also relates to a catalyst comprising the metallocene complex, to a process for making polyolefins and to the use of the polyolefins for making articles.
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