An energy storage system (ESS) for a vehicle propulsion system includes a first battery electrically coupled to a first voltage bus, a second battery electrically coupled to a second voltage bus, and a bidirectional DC/DC power converter electrically coupled to the voltage buses. A starter for cranking an engine is electrically coupled to the first voltage bus. A controller executes computer code stored in memory. The computer code is configured to operate the converter in a boost mode to transfer power from the second voltage bus to the first voltage bus, in response to the controller determining that: a power capability of the first battery is below a power demand on the first voltage bus; a state of charge of the first battery is below a state of charge threshold; or a temperature of the first battery is below a temperature threshold.