Invention Grant
- Patent Title: Processes to produce poly alpha-olefin trimers
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Application No.: US17360275Application Date: 2021-06-28
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Publication No.: US11525020B2Publication Date: 2022-12-13
- Inventor: Patrick C. Chen , Mark H. Li , Jennifer L. Rapp , Monica D. Lotz , Babak LotfizadehDehkordi , Craig J. Emett , Najeeb M. Kuzhiyil , Jian Yang
- Applicant: ExxonMobil Chemical Patents Inc.
- Applicant Address: US TX Baytown
- Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee Address: US TX Baytown
- Agency: Exxonmobil Chemical Patents Inc.
- Main IPC: C07C2/30
- IPC: C07C2/30 ; C07C2/32 ; C08F4/6592 ; C08F10/14 ; C08F4/659

Abstract:
The present disclosure generally relates to processes to produce alpha-olefin oligomers and poly alpha-olefins. In an embodiment, a process to produce a poly alpha-olefin (PAO) includes introducing a first alpha-olefin and a first catalyst system comprising a metallocene compound into a continuous stirred tank reactor or a continuous tubular reactor under first reactor conditions to form a first reactor effluent. The alpha-olefin is introduced to the reactor at a flow rate of about 100 g/hr or more. The first reactor effluent includes PAO dimer comprising at least 96 mol % of vinylidene and 4 mol % or less of trisubstituted vinylene and disubstituted vinylene, based on total moles of vinylidene, trisubstituted vinylene, and disubstituted vinylene. The method includes introducing the first reactor effluent, a second alpha-olefin and a second catalyst composition comprising an acid catalyst into a second reactor under second reactor conditions to form a second reactor effluent comprising PAO trimer.
Public/Granted literature
- US20220127392A1 Processes to Produce Poly Alpha-Olefin Trimers Public/Granted day:2022-04-28
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