公开(公告)号：US20240287225A1

公开(公告)日：2024-08-29

申请号：US18647691

申请日：2024-04-26

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Patrick C. Chen ,  Mark H. Li ,  Jennifer L. Rapp ,  Pramod J. Nandapurkar ,  Brian H. Wahn ,  Babak Lotfizadehdehkordi ,  Craig J. Emett ,  Najeeb M. Kuzhiyil ,  Jian Yang

IPC: C08F210/16 ,  C07C2/30 ,  C07C2/32 ,  C08F4/659 ,  C08F4/6592

CPC classification number: C08F210/16 ,  C07C2/30 ,  C07C2/32 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65922

Abstract: In at least one embodiment, a process to produce a poly alpha-olefin (PAO) includes introducing a first alpha-olefin to a first catalyst system comprising activator and a metallocene compound into a continuous stirred tank reactor or a continuous tubular reactor under first reactor conditions to form a first reactor effluent. The first alpha-olefin is introduced to the reactor at a flow rate of about 100 g/hr or more. The first reactor effluent includes at least 60 wt % of PAO dimer and 40 wt % or less of higher oligomers, where the higher oligomers are oligomers that have a degree of polymerization of 3 or more. The process includes introducing the first reactor effluent and a second alpha-olefin to a second catalyst composition including an acid catalyst in a second reactor to form a second reactor effluent comprising PAO trimer.

公开(公告)号：US20210347921A1

公开(公告)日：2021-11-11

申请号：US17239004

申请日：2021-05-03

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Patrick C. Chen ,  Jennifer L. Rapp ,  Jian Yang ,  Jo Ann M. Canich ,  Hua Zhou ,  Craig J. Emett ,  Kyle G. Lewis ,  Babak LotfizadehDehkordi

IPC: C08F10/14 ,  C08F4/659 ,  C08F4/6592 ,  C08F8/04 ,  C07C2/30 ,  C07C2/32 ,  C08F2/01 ,  C10M107/10

Abstract: The present disclosure generally relates to processes to produce alpha-olefin oligomers and poly alpha-olefins. In an embodiment, the present disclosure provides a process to produce a poly alpha-olefin (PAO), the process including: introducing a C6-C32 alpha-olefin and a catalyst system comprising activator and a metallocene compound into a continuous stirred tank reactor or a continuous tubular reactor under reaction conditions, wherein the alpha-olefin is introduced to the reactor at a flow rate of about 100 g/hr or more; and obtaining a product comprising PAO dimer and optional higher oligomers of alpha-olefin, or a combination thereof, the PAO dimer comprising 96 mol % or more of vinylidene, based on total moles of vinylidene, disubstituted vinylene, and trisubstituted vinylene in the product. In at least one embodiment, a process includes functionalizing and/or hydrogenating a PAO product of the present disclosure. In at least one embodiment, a blend includes a PAO product of the present disclosure.

公开(公告)号：US11078308B2

公开(公告)日：2021-08-03

申请号：US16537349

申请日：2019-08-09

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Patrick C. Chen ,  Mark H. Li ,  Jennifer L. Rapp ,  Monica D. Lotz ,  Babak LotfizadehDehkordi ,  Craig J. Emett ,  Najeeb M. Kuzhiyil ,  Jian Yang

IPC: C07C2/30 ,  C07C2/32 ,  C08F4/6592 ,  C08F10/14 ,  C08F4/659

Abstract: The present disclosure generally relates to processes to produce alpha-olefin oligomers and poly alpha-olefins. In an embodiment, a process to produce a poly alpha-olefin (PAO) includes introducing a first alpha-olefin and a first catalyst system comprising a metallocene compound into a continuous stirred tank reactor or a continuous tubular reactor under first reactor conditions to form a first reactor effluent. The alpha-olefin is introduced to the reactor at a flow rate of about 100 g/hr or more. The first reactor effluent includes PAO dimer comprising at least 96 mol % of vinylidene and 4 mol % or less of trisubstituted vinylene and disubstituted vinylene, based on total moles of vinylidene, trisubstituted vinylene, and disubstituted vinylene. The method includes introducing the first reactor effluent, a second alpha-olefin and a second catalyst composition comprising an acid catalyst into a second reactor under second reactor conditions to form a second reactor effluent comprising PAO trimer.

公开(公告)号：US12084624B2

公开(公告)日：2024-09-10

申请号：US17997795

申请日：2021-05-10

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Monica D. Lotz ,  Kyle G. Lewis ,  Christine M Henry ,  Craig J. Emett

IPC: C10M107/02 ,  C08F8/00 ,  C08F10/00 ,  C10M105/06 ,  C10M127/04 ,  C10N20/02 ,  C10N30/02 ,  C10N30/10 ,  C10N40/00 ,  C10N40/04 ,  C10N40/08 ,  C10N40/25 ,  C10N40/30 ,  C10N50/10

CPC classification number: C10M107/02 ,  C08F8/00 ,  C08F10/00 ,  C10M105/06 ,  C10M127/04 ,  C10M2203/06 ,  C10M2203/065 ,  C10M2205/0206 ,  C10N2020/02 ,  C10N2030/02 ,  C10N2030/10 ,  C10N2040/04 ,  C10N2040/08 ,  C10N2040/25 ,  C10N2040/30 ,  C10N2040/40 ,  C10N2050/10

Abstract: The present disclosure generally relates to alkylated aromatic compounds useful as basestocks and additives for high viscosity applications. In an embodiment is provided an alkylated aromatic compound. In another embodiment is provided a lubricant formulation that includes an alkylated aromatic compound. In another embodiment is provided a lubricant formulation that includes an alkylated aromatic compound, an additive, and optionally, a Group III basestock, Group IV basestock, Group V basestock, or a combination thereof, the Group V basestock being different than the alkylated aromatic compound. In another embodiment is provided a method of forming a lubricant formulation that includes introducing a mPAO, an aromatic compound, and an acid catalyst to a reactor under reactor conditions to form an alkylated aromatic compound; and introducing the alkylated aromatic compound to an additive to form a lubricant formulation.

公开(公告)号：US20210284769A1

公开(公告)日：2021-09-16

申请号：US17240437

申请日：2021-05-03

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Patrick C. Chen ,  Mark H. Li ,  Jennifer L. Rapp ,  Pramod J. Nandapurkar ,  Brian H. Wahn ,  Babak LotfizadehDehkordi ,  Craig J. Emett ,  Najeeb M. Kuzhiyil ,  Jian Yang

IPC: C08F210/16 ,  C08F4/659 ,  C08F4/6592 ,  C07C2/30 ,  C07C2/32

Abstract: In at least one embodiment, a process to produce a poly alpha-olefin (PAO) includes introducing a first alpha-olefin to a first catalyst system comprising activator and a metallocene compound into a continuous stirred tank reactor or a continuous tubular reactor under first reactor conditions to form a first reactor effluent. The first alpha-olefin is introduced to the reactor at a flow rate of about 100 g/hr or more. The first reactor effluent includes at least 60 wt % of PAO dimer and 40 wt % or less of higher oligomers, where the higher oligomers are oligomers that have a degree of polymerization of 3 or more. The process includes introducing the first reactor effluent and a second alpha-olefin to a second catalyst composition including an acid catalyst in a second reactor to form a second reactor effluent comprising PAO trimer.

公开(公告)号：US20230227746A1

公开(公告)日：2023-07-20

申请号：US17997795

申请日：2021-05-10

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Monica D. Lotz ,  Kyle G. Lewis ,  Christine M Henry ,  Craig J. Emett

IPC: C10M107/02 ,  C08F10/00

CPC classification number: C10M107/02 ,  C08F10/00 ,  C10M2205/0206 ,  C10N2020/02

Abstract: The present disclosure generally relates to alkylated aromatic compounds useful as basestocks and additives for high viscosity applications. In an embodiment is provided an alkylated aromatic compound. In another embodiment is provided a lubricant formulation that includes an alkylated aromatic compound. In another embodiment is provided a lubricant formulation that includes an alkylated aromatic compound, an additive, and optionally, a Group III basestock, Group IV basestock, Group V basestock, or a combination thereof, the Group V basestock being different than the alkylated aromatic compound. In another embodiment is provided a method of forming a lubricant formulation that includes introducing a mPAO, an aromatic compound, and an acid catalyst to a reactor under reactor conditions to form an alkylated aromatic compound; and introducing the alkylated aromatic compound to an additive to form a lubricant formulation.

公开(公告)号：US20220127392A1

公开(公告)日：2022-04-28

申请号：US17360275

申请日：2021-06-28

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Patrick C. Chen ,  Mark H. Li ,  Jennifer L. Rapp ,  Monica D. Lotz ,  Babak LotfizadehDehkordi ,  Craig J. Emett ,  Najeeb M. Kuzhiyil ,  Jian Yang

IPC: C08F10/14 ,  C08F4/659 ,  C08F4/6592 ,  C07C2/30 ,  C07C2/32

Abstract: The present disclosure generally relates to processes to produce alpha-olefin oligomers and poly alpha-olefins. In an embodiment, a process to produce a poly alpha-olefin (PAO) includes introducing a first alpha-olefin and a first catalyst system comprising a metallocene compound into a continuous stirred tank reactor or a continuous tubular reactor under first reactor conditions to form a first reactor effluent. The alpha-olefin is introduced to the reactor at a flow rate of about 100 g/hr or more. The first reactor effluent includes PAO dimer comprising at least 96 mol % of vinylidene and 4 mol % or less of trisubstituted vinylene and disubstituted vinylene, based on total moles of vinylidene, trisubstituted vinylene, and disubstituted vinylene. The method includes introducing the first reactor effluent, a second alpha-olefin and a second catalyst composition comprising an acid catalyst into a second reactor under second reactor conditions to form a second reactor effluent comprising PAO trimer.

公开(公告)号：US11021553B2

公开(公告)日：2021-06-01

申请号：US16537364

申请日：2019-08-09

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Patrick C. Chen ,  Jennifer L. Rapp ,  Jian Yang ,  Jo Ann M. Canich ,  Hua Zhou ,  Craig J. Emett ,  Kyle G. Lewis ,  Babak LotfizadehDehkordi

IPC: C07C2/30 ,  C07C2/32 ,  C08F4/6592 ,  C08F10/14 ,  C08F4/659 ,  C08F2/01 ,  C08F8/04 ,  C10M107/10

Abstract: The present disclosure generally relates to processes to produce alpha-olefin oligomers and poly alpha-olefins. In an embodiment, the present disclosure provides a process to produce a poly alpha-olefin (PAO), the process including: introducing a C6-C32 alpha-olefin and a catalyst system comprising activator and a metallocene compound into a continuous stirred tank reactor or a continuous tubular reactor under reaction conditions, wherein the alpha-olefin is introduced to the reactor at a flow rate of about 100 g/hr or more; and obtaining a product comprising PAO dimer and optional higher oligomers of alpha-olefin, or a combination thereof, the PAO dimer comprising 96 mol % or more of vinylidene, based on total moles of vinylidene, disubstituted vinylene, and trisubstituted vinylene in the product. In at least one embodiment, a process includes functionalizing and/or hydrogenating a PAO product of the present disclosure. In at least one embodiment, a blend includes a PAO product of the present disclosure.

公开(公告)号：US11525020B2

公开(公告)日：2022-12-13

申请号：US17360275

申请日：2021-06-28

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Patrick C. Chen ,  Mark H. Li ,  Jennifer L. Rapp ,  Monica D. Lotz ,  Babak LotfizadehDehkordi ,  Craig J. Emett ,  Najeeb M. Kuzhiyil ,  Jian Yang

IPC: C07C2/30 ,  C07C2/32 ,  C08F4/6592 ,  C08F10/14 ,  C08F4/659

Abstract: The present disclosure generally relates to processes to produce alpha-olefin oligomers and poly alpha-olefins. In an embodiment, a process to produce a poly alpha-olefin (PAO) includes introducing a first alpha-olefin and a first catalyst system comprising a metallocene compound into a continuous stirred tank reactor or a continuous tubular reactor under first reactor conditions to form a first reactor effluent. The alpha-olefin is introduced to the reactor at a flow rate of about 100 g/hr or more. The first reactor effluent includes PAO dimer comprising at least 96 mol % of vinylidene and 4 mol % or less of trisubstituted vinylene and disubstituted vinylene, based on total moles of vinylidene, trisubstituted vinylene, and disubstituted vinylene. The method includes introducing the first reactor effluent, a second alpha-olefin and a second catalyst composition comprising an acid catalyst into a second reactor under second reactor conditions to form a second reactor effluent comprising PAO trimer.

公开(公告)号：US11180709B2

公开(公告)日：2021-11-23

申请号：US16968750

申请日：2019-01-14

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Craig J. Emett ,  Babak LotfizadehDehkordi ,  Najeeb M. Kuzhiyil ,  Wenning W. Han ,  Heinrich R. Braun

IPC: C10M107/10 ,  C09K5/10 ,  C10N40/00 ,  C10N30/00 ,  C10N40/08 ,  C10N40/04 ,  C10N30/02

Abstract: Disclosed are functional fluids such as automotive engine transmission fluids, clutch fluids, gearbox fluids, electric motor fluids, and/or battery packing cooling fluids comprising a low-viscosity, low-volatility Polyalpha-olefin base stock, and processes for lubricating and/or cooling an engine transmission, an electric motor, and/or a battery packing using such functional fluids.