Invention Grant
- Patent Title: Zwitterionic copolymers, coating compositions, articles, and coating methods
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Application No.: US17309422Application Date: 2019-12-11
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Publication No.: US11634525B2Publication Date: 2023-04-25
- Inventor: Federica Sgolastra , Semra Colak Atan , George W. Griesgraber , Zachary J. Malmberg
- Applicant: 3M INNOVATIVE PROPERTIES COMPANY
- Applicant Address: US MN St. Paul
- Assignee: 3M INNOVATIVE PROPERTIES COMPANY
- Current Assignee: 3M INNOVATIVE PROPERTIES COMPANY
- Current Assignee Address: US MN St. Paul
- Agent Jean A. Lown
- International Application: PCT/IB2019/060670 WO 20191211
- International Announcement: WO2020/128732 WO 20200625
- Main IPC: C08F230/02
- IPC: C08F230/02 ; C08F220/60 ; C09D133/14 ; C09D143/02 ; C08F220/38 ; C09D133/26

Abstract:
Zwitterionic copolymers, coating compositions (e.g., aqueous coating compositions and articles containing such copolymers, and methods of coating such coating compositions; wherein the copolymer includes: (a) first monomeric units derived from monomers of Formula (I) CH2═CR1—(CO)—X—R2—[-Q-R3—]n—Y (I) or salts thereof, wherein: R1 is hydrogen or methyl; X is oxy or —NH—; R2 is an alkylene optionally including catenary oxygen; R3 is an alkylene; Q is —(CO)O—, —NR4—(CO)—NR4—, or —(CO)—NR4—; R4 is hydrogen or alkyl; n is equal to 0 or 1; and Y is phosphonic acid, phosphonate, phosphoric acid, or phosphate; and (b) second monomeric units derived from monomers of Formula (II) CH2═CR1—(CO)—X—R2—[-Q-R3—]n—[NR5R6]+—R7—Z— (II) wherein: R1 is hydrogen or methyl; X is oxy or —NH—; R2 is alkylene optionally including catenary oxygen; R3 is alkylene; Q is —(CO)O—, —NR4—(CO)—NR4—, or —(CO)—NR4-; R4 is hydrogen or alkyl; n is equal to 0 or 1; R5 and R6 are each independently an alkyl, aryl, or a combination thereof, or R5 and R6 both combine with the nitrogen to which they are both attached to form a heterocyclic ring having 3 to 7 ring members; R7 is alkylene; and Z″ is carboxylate or sulfonate. CH2═CR1—(CO)—X—R2—[-Q-R3-]n—Y (I) CH2═CR1—(CO)—X—R2—[-Q-R3—]n—[NR5R6]+—R7—Z− (II)
Public/Granted literature
- US20220025093A1 ZWITTERIONIC COPOLYMERS, COATING COMPOSITIONS, ARTICLES, AND COATING METHODS Public/Granted day:2022-01-27
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