A hydrophobic polyvinyl alcohol and a method for preparing hydrophobic polyvinyl alcohol are provided. The hydrophobic polyvinyl alcohol includes a first repeat unit represented by Formula (I), a second repeat unit represented by Formula (II), and a third repeat unit represented by Formula (III)




wherein R1 is —Si(R2)3,





R2 is independently C1-6 alkoxy group, C6-18 alkyl group, or C6-22 alkenyl group, and at least one R2 is C6-18 alkyl group or C6-22 alkenyl group; R3 and R4 are independently C6-18 alkyl group or C6-22 alkenyl group; j is 3 to 7; and k is 1 to 30.