The disclosed adhesive sheet exhibits high anchoring performance and where separation between the substrate and the adhesive layer substantially does not occur when unwinding or re-peeling in actual applications. The adhesive sheet comprises a substrate including a urethane polymer component at least at a portion of a surface and a silicone adhesive layer that is in contact with the urethane polymer component, wherein the urethane polymer having a chain extender-derived hard segment and a polyoxyalkylene polyol-derived soft segment.