The present invention discloses a method of constructing a solid slippery surface, belonging to the technical field of preparation of lubricating materials. The method of constructing a solid slippery surface comprises (1) constructing a metal oxide coating on the surface of a metal substrate by anodic oxidation, and then modifying the metal oxide coating using a low surface energy material to afford a superhydrophobic coating; and (2) fulling mixing photothermal nanoparticles and solid paraffin, followed by infusing the mixture onto the surface of the superhydrophobic coating to afford the solid slippery surface. The preparation method of the present invention is performed in a simple process and is environmentally friendly. The solid slippery surface constructed in the present invention has excellent photothermal and anti-icing performance, making some improvements in the field of copper metal anti-icing.