Invention Grant
- Patent Title: Method for making an unmodified jute supported catalyst
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Application No.: US18606656Application Date: 2024-03-15
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Publication No.: US12102983B2Publication Date: 2024-10-01
- Inventor: M. Nasiruzzaman Shaikh
- Applicant: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS
- Applicant Address: SA Dhahran
- Assignee: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS
- Current Assignee: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS
- Current Assignee Address: SA Dhahran
- Agency: Oblon, McClelland, Maier & Neustadt, L.L.P.
- The original application number of the division: US16732579 2020.01.02
- Main IPC: B01J23/44
- IPC: B01J23/44 ; B01J31/06 ; B01J35/30 ; B01J35/40 ; B01J37/04 ; B01J37/08 ; B01J37/16 ; C07C1/26

Abstract:
A solid-supported Pd catalyst is suitable for C—C bond formation, e.g., via Suzuki-Miyaura and Mizoroki-Heck cross-coupling reactions, with a support that is reusable, cost-efficient, regioselective, and naturally available. Such catalysts may contain Pd nanoparticles on jute plant sticks (GS), i.e., Pd@GS, and may be formed by reducing, e.g., K2PdCl4 with NaBH4 in water, and then used this as a “dip catalyst.” The dip catalyst can catalyze Suzuki-Miyaura and Mizoroki-Heck cross coupling-reactions in water. The catalysts may have a homogeneous distribution of Pd nanoparticles with average dimensions, e.g., within a range of 7 to 10 nm on the solid support. Suzuki-Miyaura cross-coupling reactions may achieve conversions of, e.g., 97% with TOFs around 4692 h−1, Mizoroki-Heck reactions with conversions of, e.g., a 98% and TOFs of 237 h−1, while the same catalyst sample may be used for 7 consecutive cycles, i.e., without addition of any fresh catalyst.
Public/Granted literature
- US20240278215A1 METHOD FOR MAKING AN UNMODIFIED JUTE SUPPORTED CATALYST Public/Granted day:2024-08-22
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