发明申请
US20080081916A1 Method for Producing Optically Active Aziridine Compounds and Amine Compounds as Well as Complexes and their Intermadiates Used in this Method
失效
制备光学活性氮丙啶化合物和胺化合物以及配合物及其在该方法中使用的间隔物的方法
- 专利标题： Method for Producing Optically Active Aziridine Compounds and Amine Compounds as Well as Complexes and their Intermadiates Used in this Method
- 专利标题（中）： 制备光学活性氮丙啶化合物和胺化合物以及配合物及其在该方法中使用的间隔物的方法
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申请号： US11631166申请日： 2005-06-16
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公开(公告)号： US20080081916A1公开(公告)日： 2008-04-03
- 发明人: Tsutomu Katsuki , Kazufumi Omura , Tatsuya Uchida , Ryo Irie
- 申请人： Tsutomu Katsuki , Kazufumi Omura , Tatsuya Uchida , Ryo Irie
- 申请人地址： JP Kawaguchi-Shi
- 专利权人： JAPAN SCIENCE AND TECHNOLOGY AGENCY
- 当前专利权人： JAPAN SCIENCE AND TECHNOLOGY AGENCY
- 当前专利权人地址： JP Kawaguchi-Shi
- 优先权： JP2004-197255 20040702
- 国际申请： PCT/JP05/11059 WO 20050616
- 主分类号： C07D203/24
- IPC分类号： C07D203/24 ; C07C313/00 ; C07D203/26 ; C07F15/00 ; C07F7/02
摘要：
This invention provides a method for producing an optically active aziridine compound or amine compound, which uses as a catalyst a Ru(salen)(CO) complex represented by the following formula (I) or its enantiomer having a high stability, in a high turnover number (TON) and a high enantioselectivity. In the formula (I), Ar is represented by the following formula (VI) or (VII), wherein in the formula (VI), Xs are independently a halogen or a halogenated alkyl group and R1 and R2s are independently hydrogen or an alkyl group or a trialkylsilyl group having a carbon number of 1-4, and in the formula (VII), R3 is a bulky group.
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