To provide a process for producing an electrode-formed glass substrate, which increases the strength of a front substrate of a plasma display device.Electrodes formed on a glass substrate are covered with a lead-free glass comprising, as represented by mass %, from 30 to 50% of B2O3, from 21 to 25% of SiO2, from 10 to 35% of ZnO, from 7 to 14% in total of K2O and either one or both of Li2O and Na2O, from 0 to 10% of Al2O3, from 0 to 10% of ZrO2, and from 0 to 5% of MgO+CaO+SrO+BaO, and when the molar fractions of Li2O, Na2O and K2O are represented by l, n and k, respectively, l is at most 0.025, and l+n+k is from 0.07 to 0.13.