发明申请
- 专利标题: Hydrogenation Product of Block Copolymer or Sheet or Film of the Same
- 专利标题(中): 嵌段共聚物或其片或薄膜的氢化产物
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申请号: US11887941申请日: 2006-04-07
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公开(公告)号: US20090061248A1公开(公告)日: 2009-03-05
- 发明人: Susumu Hoshi , Yukio Yamaura
- 申请人: Susumu Hoshi , Yukio Yamaura
- 优先权: JP2005-110490 20050407
- 国际申请: PCT/JP2006/307490 WO 20060407
- 主分类号: B32B27/30
- IPC分类号: B32B27/30 ; C08F236/06 ; C08F236/10 ; C08F236/08 ; C08L53/02 ; C08K5/20 ; C08K5/09 ; C08K5/01 ; C08K5/13 ; C08K5/07
摘要:
An object of the invention is to provide a block copolymer hydrogenation product suitable for a sheet and a heat shrinkable film which are excellent in solvent resistance, rigidity, elongation and transparency, which is excellent in a balance of physical properties such as solvent resistance, natural shrinkability, low-temperature shrinkability, rigidity, transparency and low-temperature elongation, and a composition thereof. The invention relates to a block copolymer hydrogenation product having a weight ratio of a vinyl aromatic hydrocarbon and a conjugated diene of 55/45 to 95/5, a number average molecular weight measured by gel permeation chromatography (GPC) of 30,000 to 500,000 and a hydrogenation rate of 30% or more, wherein the vinyl aromatic hydrocarbon incorporated into the hydrogenation product has a block rate of 60 to 98% by weight, wherein relative to the weight of the total vinyl aromatic hydrocarbon polymer blocks, the ratio of vinyl aromatic hydrocarbon polymer blocks having a molecular weight of 50,000 or less is 80% by weight or more and the ratio of vinyl aromatic hydrocarbon polymer blocks having a molecular weight of 15,000 or less is from 10 to 80% by weight, and wherein at least one peak temperature of function tan δ in a dynamic viscoelasticity measurement of the hydrogenation product is present within the range of exceeding −80° C. to lower than −10° C.
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