发明申请
- 专利标题: Method Of Preparing And Using A Molecular Sieve
- 专利标题(中): 制备和使用分子筛的方法
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申请号: US12533745申请日: 2009-07-31
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公开(公告)号: US20100087610A1公开(公告)日: 2010-04-08
- 发明人: Stephen N. Vaughn , Machteld M. Mertens , Thomas H. Colle
- 申请人: Stephen N. Vaughn , Machteld M. Mertens , Thomas H. Colle
- 主分类号: C08F4/52
- IPC分类号: C08F4/52 ; C01B37/08 ; C07C1/00
摘要:
A crystalline microporous silicoaluminophosphate (SAPO) molecular sieve is prepared by: (a) providing a reaction mixture having a molar composition within the following ranges: P:Al from 0.75 to 1.25, Si:Al2 from 0.01 to 0.32, H2O:Al2 from 25 to 50, and R:Al2 from 1 to 3, where R designates a structure directing agent (template), and wherein the molar ratios for the aluminum, phosphorus, and silicon sources are calculated based on the oxide forms; (b) heating the mixture to a crystallization temperature of between 150° C. to 250° C. to form the crystalline molecular sieve within the reaction mixture; and (c) following crystallization in step (b), aging the crystalline molecular sieve in an alkaline liquid at a temperature below the crystallization temperature from 0.5 hour for up to 120 hours. Aging can affect both catalyst life and catalyst activity.
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