发明申请
- 专利标题: Homogeneous Process for the Hydrogenation of Carboxylic Acids and Derivatives Thereof
- 专利标题(中): 羧酸及其衍生物氢化的均相方法
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申请号: US12546187申请日: 2009-08-24
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公开(公告)号: US20100099550A1公开(公告)日: 2010-04-22
- 发明人: Melvyn Kilner , Derek Vincent Tyers , Simon Peter Crabtree , Michael Anthony Wood
- 申请人: Melvyn Kilner , Derek Vincent Tyers , Simon Peter Crabtree , Michael Anthony Wood
- 专利权人: Davy Process Technology Limited
- 当前专利权人: Davy Process Technology Limited
- 优先权: GB0210143.4 20020502
- 主分类号: B01J38/10
- IPC分类号: B01J38/10 ; C09K3/00 ; B01J38/06
摘要:
A homogenous process for the hydrogenation of the carboxylic acids and/or derivatives thereof in the presence of a catalyst comprising ruthenium, rhodium, iron, osmium or palladium, and an organic phosphine is described in which the hydrogenation is carried out in the presence of at least about 1% by weight water. A process for regenerating a catalyst comprising ruthenium, rhodium, iron, osmium or palladium and an organic phosphine is also described in which the regeneration is carried out in the presence of hydrogen and water.
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