公开(公告)号：US20240343565A1

公开(公告)日：2024-10-17

申请号：US18430817

申请日：2024-02-02

Applicant: KOREA INSTITUTE OF MACHINERY & MATERIALS

Inventor： Dae-hoon LEE ,  Sungkwon JO ,  Hong Jae KANG ,  Kwan-Tae Kim ,  Younghoon SONG

IPC: C01B3/38 ,  B01J38/10

CPC classification number: C01B3/388 ,  B01J38/10 ,  C01B2203/0261 ,  C01B2203/063 ,  C01B2203/0877 ,  C01B2203/0883 ,  C01B2203/1241 ,  C01B2203/1619

Abstract: Provided is a system for supplying a reformed product from by-product gas to a catalyst regenerator of a catalytic olefins production process. The system includes a reactor configured to mix naphtha and a catalyst to produce olefins through a cracking reaction of naphtha, and then separate the coked catalyst and olefins to discharge the coked catalyst, a catalyst regenerator configured to regenerate the coked catalyst introduced from the reactor and recirculate and supply the regenerated catalyst to the reactor, an air supplier configured to supply burning air to the catalyst regenerator, and a catalytic partial oxidation reformer configured to reform by-product gas containing methane as a main component to supply a reformed product containing hydrogen and carbon monoxide as a main component to the catalyst regenerator and regenerate the coked catalyst.

公开(公告)号：US11938470B2

公开(公告)日：2024-03-26

申请号：US17989444

申请日：2022-11-17

Applicant: Utah State University

Inventor： Foster Agblevor ,  Hossein Jahromi ,  Oleksandr Hietsoi ,  Shereen Hassan

IPC: B01J37/00 ,  B01J21/04 ,  B01J21/20 ,  B01J35/02 ,  B01J35/10 ,  B01J37/02 ,  B01J37/08 ,  B01J37/18 ,  B01J38/10 ,  C10G3/00 ,  B01J21/08

CPC classification number: B01J37/0072 ,  B01J21/04 ,  B01J21/20 ,  B01J35/023 ,  B01J35/1014 ,  B01J37/0045 ,  B01J37/009 ,  B01J37/0221 ,  B01J37/08 ,  B01J37/18 ,  B01J38/10 ,  C10G3/44 ,  C10G3/62 ,  B01J21/08 ,  B01J2523/22 ,  B01J2523/847 ,  C10G2300/1011 ,  C10G2300/70

Abstract: This disclosure relates to red mud compositions. This disclosure also relates to methods of making red mud compositions. This disclosure additionally relates to methods of using red mud compositions.

公开(公告)号：US20240091760A1

公开(公告)日：2024-03-21

申请号：US18259970

申请日：2021-12-21

Applicant: BEIJING SINGLE ATOM SITE CATALYSIS TECHNOLOGY CO., LTD

Inventor： Chao LIAN ,  Yang LI ,  Jianxing SHI ,  Mengyun WANG ,  Hongchen YANG ,  Mingliang DENG ,  Minduo WANG

IPC: B01J38/08 ,  B01J21/04 ,  B01J21/08 ,  B01J23/10 ,  B01J23/26 ,  B01J23/34 ,  B01J23/60 ,  B01J23/80 ,  B01J23/89 ,  B01J29/74 ,  B01J37/02 ,  B01J37/08 ,  B01J37/18 ,  B01J38/02 ,  B01J38/10 ,  B01J38/12 ,  C07C5/32

CPC classification number: B01J38/08 ,  B01J21/04 ,  B01J21/08 ,  B01J23/10 ,  B01J23/26 ,  B01J23/34 ,  B01J23/60 ,  B01J23/80 ,  B01J23/8913 ,  B01J23/8953 ,  B01J29/74 ,  B01J37/0201 ,  B01J37/082 ,  B01J37/18 ,  B01J38/02 ,  B01J38/10 ,  B01J38/12 ,  C07C5/325 ,  C07C2523/10 ,  C07C2523/24 ,  C07C2523/60 ,  C07C2523/80

Abstract: The present invention relates to a method for preparing, activating and regenerating a metal supported catalyst, comprising: treating a Ma-Mb-Mc metal supported catalyst at 10-700° C. by using an ammonia or nitrogen-containing organic matter, wherein the Ma metal is an active metal selected from one or more of a noble metal atom or a transition metal, the support is a common industrial porous catalyst, and the Ma metal is dispersed on the support in a state of single atomic site. According to the Md-Mb-Mc metal supported noble metal/zinc catalyst treated by the method of the present invention, the direct dehydrogenation conversion rate and selectivity of catalyzing light alkanes are remarkably improved; the method for preparing the catalyst is simple in process, the catalytic activity after regeneration is still kept, and the catalyst can be industrially produced on a large scale.

公开(公告)号：US11806698B2

公开(公告)日：2023-11-07

申请号：US17245475

申请日：2021-04-30

Applicant: UOP LLC

Inventor： Gregory J. Schrad ,  Eric Leeton ,  Rebecca Mudrock

IPC: B01J31/40 ,  B01J8/02 ,  B01J19/18 ,  B01J38/10 ,  B01J31/02

CPC classification number: B01J31/40 ,  B01J8/0242 ,  B01J19/1818 ,  B01J19/1825 ,  B01J31/0277 ,  B01J38/10

Abstract: Systems, reactors, and processes for regenerating ionic liquid using catalyst. A plurality of tubular reactors are provided having a first end and a second end and catalyst particles disposed in the tubular reactor between the first end and the second end. A line supplies separated ionic liquid catalyst to the first end of the tubular reactor. Hydrogen is also supplied. Regenerated ionic liquid catalyst is recovered from the second end of the tubular reactor. The inner surface of the tubular reactor is preferably non-corrosive or non-reactive. A fluoropolymer lining may be used. The tubular reactors are modular, and may be changed out with the catalyst inside when the catalyst are to be replaced.

公开(公告)号：US20210339236A1

公开(公告)日：2021-11-04

申请号：US17245475

申请日：2021-04-30

Applicant: UOP LLC

Inventor： Gregory J. Schrad ,  Eric Leeton ,  Rebecca Mudrock

IPC: B01J31/40 ,  B01J19/18 ,  B01J31/02 ,  B01J38/10

Abstract: Systems, reactors, and processes for regenerating ionic liquid using catalyst. A plurality of tubular reactors are provided having a first end and a second end and catalyst particles disposed in the tubular reactor between the first end and the second end. A line supplies separated ionic liquid catalyst to the first end of the tubular reactor. Hydrogen is also supplied. Regenerated ionic liquid catalyst is recovered from the second end of the tubular reactor. The inner surface of the tubular reactor is preferably non-corrosive or non-reactive. A fluoropolymer lining may be used. The tubular reactors are modular, and may be changed out with the catalyst inside when the catalyst are to be replaced.

公开(公告)号：US11135575B2

公开(公告)日：2021-10-05

申请号：US15928690

申请日：2018-03-22

Applicant: Chevron U.S.A. Inc.

Inventor： Michael John Girgis ,  Huping Luo ,  Bong Kyu Chang ,  Hye-Kyung Cho Timken ,  Steven Xugi Song ,  Michael Sean Driver

IPC: C07C2/58 ,  B01J31/40 ,  B01J31/02 ,  B01J38/10 ,  C07C2/62 ,  C10L1/06 ,  C10G29/20 ,  C10G45/60 ,  C10G47/02 ,  C10G50/00 ,  B01J35/12 ,  C07C2/56

Abstract: We provide a process for regenerating a spent acidic ionic liquid, comprising contacting the spent acidic ionic liquid with hydrogen and without an addition of a hydrogenation catalyst; wherein a conjunct polymer content is decreased in the spent acidic ionic liquid to produce regenerated acidic ionic liquid. We also provide a process for making an alkylate gasoline blending component, comprising: a) alkylating a mixture of isoparaffins and olefins using an acidic ionic liquid and an alkyl halide or a hydrogen halide, wherein a conjunct polymer accumulates in a spent acidic ionic liquid; and b) feeding the spent acidic ionic liquid and a hydrogen, and without an addition of a hydrogenation catalyst, to a regeneration reactor operated under selected hydrogenation conditions to produce a regenerated acidic ionic liquid that is used for the alkylating, wherein the conjunct polymer in the regenerated acidic ionic liquid is decreased by at least 50 wt %.

公开(公告)号：US11123719B2

公开(公告)日：2021-09-21

申请号：US16697492

申请日：2019-11-27

Applicant: Allen Artur Carl Reule ,  Natalia Semagina ,  Esteban Chornet

Inventor： Allen Artur Carl Reule ,  Natalia Semagina ,  Esteban Chornet

IPC: B01J37/18 ,  B01J29/24 ,  C07C67/37 ,  B01J29/90 ,  B01J38/10 ,  B01J29/22 ,  B01J29/40 ,  B01J29/44 ,  B01J29/46 ,  B01J29/035 ,  B01J37/30 ,  B01J29/06 ,  B01J29/10 ,  B01J29/20 ,  B01J29/12 ,  B01J29/064 ,  B01J29/072 ,  B01J29/068 ,  B01J29/14 ,  B01J29/66 ,  B01J29/67 ,  B01J29/65 ,  B01J29/72 ,  B01J29/42 ,  B01J29/68 ,  B01J29/70 ,  B01J29/76 ,  B01J29/74 ,  B01J29/18 ,  B01J37/14

Abstract: A catalyst for the carbonylation of dimethyl ether to methyl acetate. The catalyst comprises a zeolite, such as a mordenite zeolite, at least one Group IB metal, such as copper, and/or at least one Group VIII metal, such as iron, and at least one Group IIB metal, such as zinc. Such a catalyst with combined metals provides enhanced catalytic activity, improved stability, and improved selectivity to methyl acetate, and does not require a halogen promoter, as compared to a metal-free or copper only zeolite.

公开(公告)号：US20210139394A1

公开(公告)日：2021-05-13

申请号：US16492281

申请日：2018-03-02

Applicant: HALDOR TOPSØE A/S

Inventor： Poul Erik HØJLUND NIELSEN ,  Lived J. LEMUS-YEGRES ,  Rasmus Munksgård NIELSEN

IPC: C07C5/333 ,  B01J27/22 ,  B01J38/12 ,  B01J38/10

Abstract: In a process for the catalytic dehydrogenation of lower alkanes to the corresponding alkenes, a regenerable catalyst comprising iron carbide supported on a carrier is used. A small amount (below 100 ppm) of a sulfur compound, such as H2S, is added during the process.

公开(公告)号：US11000839B2

公开(公告)日：2021-05-11

申请号：US15866588

申请日：2018-01-10

Applicant: Chevron U.S.A. Inc.

Inventor： Hye Kyung Cho Timken ,  Jeff Johns ,  Rahul Shankar Bhaduri ,  Viorel Duma ,  John V. Heyse

IPC: B01J31/02 ,  B01J31/40 ,  B01D15/18 ,  B01J23/44 ,  B01J38/48 ,  C07C2/58 ,  B01J38/10 ,  B01J23/42 ,  B01J35/10 ,  B01J21/04 ,  B01J20/10 ,  B01J20/16 ,  B01J20/28 ,  B01J23/83 ,  B01J38/08 ,  B01J27/125 ,  B01J31/26

Abstract: Provided is a hydro-regeneration catalyst system, comprising: (a) a first graded bed comprising a guard bed material; and (b) a second graded bed, fluidly connected to the first graded bed, comprising a noble metal catalyst on a support having mesopores and macropores; wherein the noble metal catalyst has an average pore diameter of 20 to 1,000 nm (0.02 to 1 μm), a total pore volume of greater than 0.80 cc/g, and a macropore volume of 0.10 to 0.50 cc/g. Also provided is a guard bed system, comprising: (a) a first guard bed comprising a first adsorbent having 10 μm or larger pores with an average pore diameter of 100 to 1,000 μm; and (b) a second guard bed fluidly connected to the first guard bed, comprising a second adsorbent material having mesopores and macropores with a second average pore diameter of 20 to 1,000 nm.

公开(公告)号：US10888857B2

公开(公告)日：2021-01-12

申请号：US16010695

申请日：2018-06-18

Applicant: UOP LLC

Inventor： Elizabeth Carter ,  Douglas A. Nafis ,  Bong-Kyu Chang ,  Hye Kyung Timken ,  Huping Luo ,  Michael Girgis

IPC: C07C2/58 ,  B01J38/10 ,  B01J31/02 ,  B01J31/40 ,  C07C2/60 ,  C07C2/56

Abstract: Processes for regenerating ionic liquid catalyst by contacting the ionic liquid catalyst with hydrogen gas in a regeneration reactor. The amount of hydrogen is less than 550 SCF/BBL (97.96 m3/m3) of spent ionic liquid catalyst, or less than 500 SCF/BBL (89.05 m3/m3) of spent ionic liquid catalyst, or between 550 and 45 SCF/BBL (97.96 and 8.015 m3/m3) of spent ionic liquid catalyst, or between 500 and 50 SCF/BBL (89.05 and 8.905 m3/m3) of spent ionic liquid catalyst. Alkylation processes are also disclosed.