Abstract:
A liquid/gas reactor includes a bulk catalyst bed and means for supplying fresh feed and recycled at least partially converted liquid product stream to the bulk catalyst bed. The reactor also includes means for collecting an at least partially converted liquid product stream from the bulk catalyst bed and recycling at least a portion thereto. A minor catalyst bed extends substantially vertically through the bulk catalyst bed. Means for supplying recycled at least partially converted product stream only to the minor catalyst bed is also provided. A separating wall is disposed between the bulk catalyst bed and the minor catalyst bed.
Abstract:
In a process for producing anhydrides in a tubular reactor, gaseous reactants are passed downwardly through at least one reactor tube to a catalyst carrier where they pass into a passage defined by an inner perforated wall of a catalyst container before passing radially through the catalyst bed towards a perforated outer container wall. The reaction occurs as gas contacts the catalyst. Unreacted reactant and product exits the container though the perforated outer wall and then upwardly between an inner surface of a container skirt and the outer wall of the container and then over the end of the skirt and caused to flow downwardly between the outer surface of the skirt and the inner surface of the reactor tube where heat transfer takes place. These steps are repeated at any subsequent catalyst carrier product is then removed from the reactor outlet.
Abstract:
In a process for the production of fatty alcohol(s) a fatty acid or fatty acid mixture is subjected to esterification with a lower alkanol to form a stream comprising the corresponding lower alkyl ester or esters. The stream is vaporised and subjected to hydrogenation to form a stream comprising fatty alcohol(s) and an amount of unconverted lower alkyl ester(s). This stream is subjected to transesterification in a wax ester reactor in the presence of a solid transesterification catalyst. Fatty alcohol(s) and wax ester(s) are then separated by distillation to yield a fatty alcohol(s) product and a stream comprising wax ester(s). The stream of wax ester(s) is passed to a second hydrogenation zone to effect hydrogenation in the liquid phase to revert the wax ester(s) to fatty alcohol(s), which are returned to the distillation separation step.
Abstract:
A process for activating a reduced manganese copper catalyst comprising treating the catalyst at a temperature of more than 300° C. to about 400° C. with hydrogen.
Abstract:
A liquid/gas reactor includes a bulk catalyst bed and means for supplying fresh feed and recycled at least partially converted liquid product stream to the bulk catalyst bed. The reactor also includes means for collecting an at least partially converted liquid product stream from the bulk catalyst bed and recycling at least a portion thereto. A minor catalyst bed extends substantially vertically through the bulk catalyst bed. Means for supplying recycled at least partially converted product stream only to the minor catalyst bed is also provided. A separating wall is disposed between the bulk catalyst bed and the minor catalyst bed.
Abstract:
In a process for the separation and drying of crude carboxylic acid crystals from a slurry in a solvent, the slurry is supplied to a filter operating at pressure and at a temperature above the atmospheric boiling point of the solvent. A cake of separated crystals is removed from the filter and passed to a thermal dryer. In a system for the separation and drying of crude carboxylic acid from a slurry in a solvent, a pressure filter device has a slurry inlet and an outlet for a cake of carboxylic acid crystals. The system also has a thermal dryer and means for transporting the cake of carboxylic acid crystals from the pressure filter device to the dryer. The pressure filter device is configured to operate at a pressure and temperature above the atmospheric boiling point of the solvent.
Abstract:
In a process for the production of substitute natural gas, a feed gas is provided to a first and/or second and/or subsequent bulk methanator. The feed gas is subjected to methanation in the presence of a suitable catalyst. An at least partially reacted stream from the first bulk methanator is removed and supplied to the second and/or subsequent bulk methanator where it is subjected to further methanation. A product stream from the final bulk methanator is passed to a trim methanator train where it is subjected to further methanation. A recycle stream is removed downstream of the first, second or subsequent bulk methanator, and, in any order, passed through a compressor, subjected to cooling and then supplied to a trim and/or recycle methanator for further methanation before being recycled to the first and/or second and/or subsequent methanator.
Abstract:
In a process for the separation of carboxylic acid from a slurry in a solvent, a slurry with crystals of carboxylic acid is supplied to a filter operating at pressure and at a temperature above the atmospheric boiling point of the solvent. Inert gas is mixed with the solvent and the mixture is supplied to the filter. A cake of separated crystals is removed from the filter. Inert gas removed from the filter is not recycled. In a system for performing such separation, a pressure filter device has a slurry inlet, and an outlet. Means for mixing inert gas and solvent, and means for supplying the mixture to the pressure filter are provided. The pressure filter device is configured to operate at pressure and at a temperature above the atmospheric boiling point of the solvent. The system does not include means for recycling inert gas removed from the filter.
Abstract:
A reactor system, plant and a process for the production of methanol from synthesis gas is described in which the reactor system comprises: (a) a first reactor adapted to be maintained under methanol synthesis conditions having inlet means for supply of synthesis gas and outlet means for recovery of a first methanol-containing stream, said first reactor being charged with a first volume of a methanol synthesis catalyst through which the synthesis gas flows and on which in use, partial conversion of the synthesis gas to a product gas mixture comprising methanol and un-reacted synthesis gas will occur adiabatically; and (b) a second reactor adapted to be maintained under methanol synthesis conditions having inlet means for supply of the gaseous first methanol-containing stream, outlet means for recovery of a second methanol-containing stream and cooling means, said second reactor being charged with a second volume of a methanol synthesis catalyst through which the gaseous first methanol-containing stream flows and on which, in use, further conversion of the synthesis gas to a product gas mixture comprising methanol will occur.
Abstract:
Process for conversion of syngas to liquid hydrocarbons using a catalyst composition containing a support and a Fischer-Tropsch metal for the conversion of syngas to liquid hydrocarbons, in which a silylating compound modifier is added to the catalyst composition during catalyst preparation or during a post-treatment stage.