发明申请
US20110294971A1 Telechelic Olefin Metathesis Polymers from Renewable Feedstocks 有权
来自可再生原料的非线性烯烃复分解聚合物

Telechelic Olefin Metathesis Polymers from Renewable Feedstocks
摘要:
Olefin metathesis polymerization reactions are disclosed, and more particularly ring-opening metathesis polymerization of cyclic olefins with olefinic compounds, such as are derived from seed oils and the like, to form telechelic polymers. In one aspect, a method is provided for carrying out a catalytic ring-opening metathesis polymerization reaction, comprising contacting at least one olefinic compound with at least one cyclic olefin, in the presence of a ruthenium alkylidene olefin metathesis catalyst under conditions effective to allow ring-opening metathesis polymerization of the cyclic olefin, whereby the cyclic olefin polymer formed is terminated with the olefinic compound. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and industrial chemistry.
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