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    METHOD AND COMPOSITION FOR IMPROVING ADHESION OF METATHESIS COMPOSITIONS TO SUBSTRATES
    3.
    发明申请
    METHOD AND COMPOSITION FOR IMPROVING ADHESION OF METATHESIS COMPOSITIONS TO SUBSTRATES 审中-公开

    公开(公告)号：US20170130089A1

    公开(公告)日：2017-05-11

    申请号：US15413703

    申请日：2017-01-24

    申请人： MATERIA, INC.

    发明人： Anthony R. STEPHEN ,  Christopher J. CRUCE ,  Mark S. TRIMMER ,  Michael A. GIARDELLO

    IPC分类号： C09D143/00

    CPC分类号： C09D143/00 ,  C09D143/04

    摘要： A method of improving the adhesion of metathesis compositions, such as ring-opening metathesis polymerization (ROMP) compositions, to a substrate is disclosed, in which an adhesion promoter is added to a polymerizable resin composition in order to improve the adhesion of the polymerizing resin to a substrate material. The addition of the adhesion promoter has been found to provide beneficial improvements in the adhesion of metathesis, especially ROMP, compositions to substrates, particularly glass surfaces, leading to improved characteristics in ROMP materials formed therefrom. The adhesion promoter generally comprises a functionalized silane compound and a peroxide compound. A ROMP composition is further disclosed comprising a cyclic olefin, a ROMP metathesis catalyst, and the adhesion promoter. Polymer products produced via metathesis (ROMP) reactions of the invention may be utilized to provide a wide range of materials and in a variety of composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.

    Supported olefin metathesis catalysts
    4.
    发明授权
    Supported olefin metathesis catalysts 有权
    负载型烯烃复分解催化剂

    公开(公告)号：US09427731B2

    公开(公告)日：2016-08-30

    申请号：US13488406

    申请日：2012-06-04

    申请人： Daryl Allen ,  Michael Giardello

    发明人： Daryl Allen ,  Michael Giardello

    IPC分类号： B01J31/22 ,  C07F15/00 ,  C07C6/04 ,  C07C67/333 ,  C07C67/475 ,  C08G61/08 ,  B01J31/16

    CPC分类号： B01J31/2278 ,  B01J31/1633 ,  B01J31/1641 ,  B01J31/2208 ,  B01J31/2273 ,  B01J31/2295 ,  B01J2231/543 ,  B01J2531/821 ,  C07B2200/11 ,  C07C6/04 ,  C07C67/333 ,  C07C67/475 ,  C07C2531/22 ,  C07C2601/10 ,  C07F15/0046 ,  C08G61/08 ,  C08G2261/418 ,  C08G2261/419 ,  Y02P20/52 ,  C07C11/02 ,  C07C69/74 ,  C07C69/593 ,  C07C69/18

    摘要： Supported olefin metathesis catalysts are disclosed, and more particularly, a supported catalyst complex comprising a catalyst composed of a Group 8 transition metal complex comprising a labile ligand and a non-labile ligand and a support, wherein the metal complex and the support are linked together by one or more linkers, in which one of the linkers connects the labile ligand of the complex to the support and the same or a different linker connects the non-labile ligand of the complex to the support. A method for preparing a supported catalyst complex is further disclosed. The invention further relates to the use of the supported olefin metathesis catalyst in performing metathesis reactions. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and industrial and fine chemicals chemistry.

    摘要翻译： 公开了负载型烯烃复分解催化剂，更具体地，涉及包含由包含不稳定配体和非不稳定配体的第8族过渡金属络合物和载体构成的催化剂的载体催化剂络合物，其中金属络合物和载体连接在一起 一个或多个接头，其中一个接头将复合物的不稳定配体连接到载体上，并且相同或不同的接头将复合物的非不稳定配体连接到载体上。 还公开了一种制备负载型催化剂络合物的方法。 本发明还涉及负载的烯烃复分解催化剂在进行复分解反应中的用途。 本发明在催化，有机合成，聚合物化学，工业和精细化学品化学领域具有实用价值。

    Chelating carbene ligand precursors and their use in the synthesis of metathesis catalysts
    8.
    发明授权
    Chelating carbene ligand precursors and their use in the synthesis of metathesis catalysts 有权
    螯合卡宾配体前体及其在复分解催化剂合成中的应用

    公开(公告)号：US08754249B2

    公开(公告)日：2014-06-17

    申请号：US13542607

    申请日：2012-07-05

    申请人： Richard L. Pederson ,  Jason K. Woertink ,  Christopher M. Haar ,  David E. Gindelberger ,  Yann Schrodi

    发明人： Richard L. Pederson ,  Jason K. Woertink ,  Christopher M. Haar ,  David E. Gindelberger ,  Yann Schrodi

    IPC分类号： C07F15/00 ,  B01J31/00

    CPC分类号： B01J31/2414 ,  B01J31/1805 ,  B01J31/2204 ,  B01J31/2208 ,  B01J31/2265 ,  B01J31/2273 ,  B01J31/2278 ,  B01J31/2404 ,  B01J2231/50 ,  B01J2231/54 ,  B01J2231/543 ,  B01J2531/821 ,  B01J2531/825 ,  C07F15/002 ,  C07F15/0046

    摘要： Chelating ligand precursors for the preparation of olefin methathesis catalysts are disclosed. The resulting catalysts are air stable monomeric species capable of promoting various methathesis reactions efficiently, which can be recovered from the reaction mixture and reused. Internal olefin compounds, specifically beta-substituted styrenes, are used as ligand precursors. Compared to terminal olefin compounds such as unsubstituted styrenes, the beta-substituted styrenes are easier and less costly to prepare, and more stable since they are less prone to spontaneous polymerization. Methods of preparing chelating-carbene methathesis catalysts without the use of CuCl are disclosed. This eliminates the need for CuCl by replacing it with organic acids, mineral acids, mild oxidants or even water, resulting in high yields of Hoveyda-type methathesis catalysts. The invention provides an efficient method for preparing chelating-carbene metathesis catalysts by reacting a suitable ruthenium complex in high concentrations of the ligand precursors followed by crystallization from an organic solvent.

    摘要翻译： 公开了用于制备烯烃复合催化剂的螯合配体前体。 得到的催化剂是能够有效促进各种复合反应的空气稳定的单体物质，其可以从反应混合物中回收并重复使用。 使用内部烯烃化合物，特别是β-取代的苯乙烯作为配体前体。 与末端烯烃化合物如未取代的苯乙烯相比，β-取代的苯乙烯更容易制备成本更低，更稳定，因为它们不易于自发聚合。 公开了不使用CuCl制备螯合 - 卡宾络合催化剂的方法。 这通过用有机酸，无机酸，温和氧化剂甚至水代替它来消除对CuCl的需要，导致Hoveyda型复分解催化剂的高产率。 本发明提供了一种制备螯合碳烯复分解催化剂的有效方法，该方法是通过在高浓度配体前体中合适的钌络合物，然后从有机溶剂中结晶而制备。

    METHOD FOR IN-SITU FORMATION OF METATHESIS CATALYSTS
    10.
    发明申请
    METHOD FOR IN-SITU FORMATION OF METATHESIS CATALYSTS 审中-公开

    公开(公告)号：US20130204026A1

    公开(公告)日：2013-08-08

    申请号：US13636918

    申请日：2011-03-24

    申请人： Yann Schrodi

    发明人： Yann Schrodi

    IPC分类号： B01J31/12 ,  C07C6/04

    CPC分类号： C07F15/0046 ,  B01J31/122 ,  B01J31/2265 ,  B01J31/2295 ,  B01J31/2404 ,  B01J2231/543 ,  B01J2531/821 ,  B01J2531/825 ,  C07C6/04 ,  C07C67/333 ,  C07C2601/10 ,  C07D207/46 ,  C07D207/48 ,  C07D211/94 ,  C07D211/96 ,  C07D223/04 ,  C07C69/74

    摘要： Synthetic methods for the in-situ formation of olefin metathesis catalysts are disclosed, as well as the use of such catalysts in metathesis reactions of olefins and olefin compounds. In one aspect, a method is provided for synthesizing an organometallic compound of the formula comprising contacting a precursor compound of the formula (X1X2MLjL1kL3m)i with an acetylenic compound comprising a chelating moiety, optionally, in the presence of a neutral electron donor, wherein M is a Group 8 transition metal, L, L1, L2, and L3 are neutral electron donors, X1 and X2 are anionic ligands, j is 1, 2, or 3; k is zero, 1, or 2; m is zero or 1; n is 1 or 2; and i is an integer; with the proviso that k is zero when the precursor compound is contacted with the acetylenic compound in the presence of the neutral electron donor, and R1 and R2 are independently selected from hydrocarbyl, substituted hydrocarbyl, heteroatom-containing hydrocarbyl, substituted heteroatom-containing hydrocarbyl, and functional groups, wherein R1 and R2 are linked and together form one or more cyclic groups, R2 and L2 are linked and together form one or more cyclic groups, and any other two or more of X1, X2, L1, L2, L3, R1, and R2 can be taken together to form one or more cyclic groups. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and industrial and fine chemicals chemistry.