发明申请
- 专利标题: MODIFIED MOLECULAR SIEVE CHARACTERIZED BY IMPROVED SODIUM-RESISTING CONTAMINATION ACTIVITY AND PREPARATION METHOD THEREOF
- 专利标题(中): 改进的耐酸性污染活性表征的改性分子筛及其制备方法
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申请号: US13505224申请日: 2009-12-01
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公开(公告)号: US20120213695A1公开(公告)日: 2012-08-23
- 发明人: Xionghou Gao , Dong Ji , Haitao Zhang , Hongchang Duan , Di Li , ZhengGuo Tan , Yi Su , Chenxi Zhang , Yi Wang , Yanqing Ma , Yanbo Sun
- 申请人: Xionghou Gao , Dong Ji , Haitao Zhang , Hongchang Duan , Di Li , ZhengGuo Tan , Yi Su , Chenxi Zhang , Yi Wang , Yanqing Ma , Yanbo Sun
- 申请人地址: CN Dongcheng District
- 专利权人: PetroChina Company Limited
- 当前专利权人: PetroChina Company Limited
- 当前专利权人地址: CN Dongcheng District
- 优先权: CN200910237006.X 20091030
- 国际申请: PCT/CN09/01352 WO 20091201
- 主分类号: C01B39/38
- IPC分类号: C01B39/38
摘要:
Modified molecular sieve characterized by improved sodium-resisting contamination activity and preparation method thereof are provided. The method comprises: adding molecular sieve in phosphorus-containing organic solution, and reacting for 10-200 minutes at temperature of 70-200° C. and pressure of 0.2-1.2 MPa, and then filtering, drying and calcining. The said modified molecular sieve contains 90-99 wt. % molecular sieve as dry basis and 1-10 wt. % phosphorus as oxide. The said method can improve the capability of sodium-resisting contamination effectively, and its technology is simple and fits the existing catalyst production apparatus and process. The said modified molecular sieve has high sodium-resisting contamination activity, and the model catalyst by sodium contamination has high activity retention.