Charging service vehicle networks are among the embodiments disclosed herein, including battery module-powered EV charging roadside service vehicles. Battery modules are removably mounted to the service vehicles and manually exchanged within a system of battery module storage locations. Some embodiments provide resupply vehicles for delivering battery modules between storage locations and/or service vehicles, and may be used to exchange battery modules. Controllers are used to reserve battery modules at the storage locations to ensure availability for high priority activities. Some storage locations have charging apparatus to recharge battery modules stored there, and some storage locations are repositionable mobile units. Multiple tiers or levels of system controllers used by service vehicles to control centers are implemented to manage operations and optimize usage of battery modules and charging services across wide areas, including providing additional service vehicles to supply temporary needs for charging services.