发明申请
- 专利标题: NANOMETER-SIZED COPPER-BASED CATALYST, PRODUCTION METHOD THEREOF, AND ALCOHOL PRODUCTION METHOD USING THE SAME THROUGH DIRECT HYDROGENATION OF CARBOXYLIC ACID
- 专利标题(中): 基于纳米尺寸铜的催化剂,其生产方法和使用相同方法通过直接加氢羧酸制备方法
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申请号: US13641813申请日: 2011-04-21
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公开(公告)号: US20130030224A1公开(公告)日: 2013-01-31
- 发明人: Hee Soo Kim , Seong Ho Lee , Young Seek Yoon , Seung Hoon Oh , Young Min Chung , Ok Youn Kim , Hee Jung Jeon
- 申请人: Hee Soo Kim , Seong Ho Lee , Young Seek Yoon , Seung Hoon Oh , Young Min Chung , Ok Youn Kim , Hee Jung Jeon
- 申请人地址: KR Jongro-gu, Seoul
- 专利权人: SK INNOVATION CO., LTD.
- 当前专利权人: SK INNOVATION CO., LTD.
- 当前专利权人地址: KR Jongro-gu, Seoul
- 优先权: KR1020100036679 20100421; KR1020100072312 20100727
- 国际申请: PCT/KR11/02874 WO 20110421
- 主分类号: B01J23/80
- IPC分类号: B01J23/80 ; B01J23/72 ; C07C29/149 ; B82Y30/00 ; B82Y40/00
摘要:
Disclosed is a nano-sized Cu based catalyst and a method of preparing the same including dissolving, in an aqueous solution, a first component comprising a Cu precursor, a second component precursor comprising one or more selected from the group consisting of a transition metal, an alkaline earth metal and a Group IIIb metal, and a third component precursor comprising one or more selected from the group consisting of alumina, silica, silica-alumina, magnesia, titania, zirconia and carbon and then performing stirring; precipitating the stirred mixture solution using Na2CO3 and NaOH to form a catalyst precursor precipitate; and washing and filtering the formed catalyst precursor precipitate. Also a method of preparing alcohol is provided, including reacting hydrogen with carboxylic acid including a single acid or an acid mixture of two or more acids derived from a microorganism fermented solution, using the nano-sized Cu based catalyst.