- 专利标题: NICKEL MANGANESE COMPOSITE HYDROXIDE PARTICLES AND MANUFACTURING METHOD THEREOF, CATHODE ACTIVE MATERIAL FOR A NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY AND MANUFACTURING METHOD THEREOF, AND A NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY
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申请号: US13520915申请日: 2011-08-26
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公开(公告)号: US20130078520A1公开(公告)日: 2013-03-28
- 发明人: Hiroyuki Toya , Kazuomi Ryoshi , Toshiyuki Osako
- 申请人: Hiroyuki Toya , Kazuomi Ryoshi , Toshiyuki Osako
- 申请人地址: JP Tokyo
- 专利权人: SUMITOMO METAL MINING CO., LTD.
- 当前专利权人: SUMITOMO METAL MINING CO., LTD.
- 当前专利权人地址: JP Tokyo
- 优先权: JP2011-127763 20110607
- 国际申请: PCT/JP2011/069350 WO 20110826
- 主分类号: H01M4/52
- IPC分类号: H01M4/52 ; H01M4/525
摘要:
Provided are nickel manganese composite hydroxide particles that are a precursor for forming cathode active material comprising lithium nickel manganese composite oxide having hollow structure of particles having a small and uniform particle size for obtaining a non-aqueous electrolyte secondary battery having high capacity, high output and good cyclability.When obtaining the nickel manganese composite hydroxide particles from a crystallization reaction, an aqueous solution for nucleation, which includes at least a metallic compound that contains nickel and a metallic compound that contains manganese, and does not include a complex ion formation agent that forms complex ions with nickel, manganese and cobalt, is controlled so that the temperature of the solution is 60° C. or greater, and so that the pH value that is measured at a standard solution temperature of 25° C. is 11.5 to 13.5, and after nucleation is performed, an aqueous solution for particle growth, which includes the nuclei that were formed in the nucleation step and does not substantially include a complex ion formation agent that forms complex ions with nickel, manganese and cobalt, is controlled so that the temperature of the solution is 60° C. or greater, and so that the pH value that is measured at a standard solution temperature of 25° C. is 9.5 to 11.5, and is less than the pH value in the nucleation step.