公开(公告)号：US20120270107A1

公开(公告)日：2012-10-25

申请号：US13513244

申请日：2010-12-02

申请人： Hiroyuki Toya ,  Shin Imaizumi ,  Kensaku Mori ,  Atsushi Fukui ,  Kenji Ikeuchi ,  Kazuomi Ryoshi ,  Toshiyuki Osako ,  Hiroki Nagai

发明人： Hiroyuki Toya ,  Shin Imaizumi ,  Kensaku Mori ,  Atsushi Fukui ,  Kenji Ikeuchi ,  Kazuomi Ryoshi ,  Toshiyuki Osako ,  Hiroki Nagai

IPC分类号： H01M4/131

CPC分类号： H01M4/505 ,  C01G53/00 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/52 ,  C01P2004/61 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/525 ,  H01M10/052 ,  Y02T10/7011

摘要： An object of the present invention is to provide nickel cobalt manganese composite hydroxide particles having a small particle diameter and a uniform particle size distribution, and a method for producing the same.[Solution]A method for producing a nickel cobalt manganese composite hydroxide by a crystallization reaction is provided. The method includes: a nucleation step of performing nucleation by controlling a pH of an aqueous solution for nucleation including metal compounds containing nickel, cobalt and manganese, and an ammonium ion donor to 12.0 to 14.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard; and a particle growth step of growing nuclei by controlling a pH of an aqueous solution for particle growth containing nuclei formed in the nucleation step to 10.5 to 12.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard.

摘要翻译： 本发明的目的是提供具有小粒径和均匀粒度分布的镍钴锰复合氢氧化物颗粒及其制造方法。 [解决方案]提供了通过结晶反应制造镍钴锰复合氢氧化物的方法。 该方法包括：通过将包含镍，钴和锰的金属化合物和铵离子给体的成核水溶液的pH控制在液体温度下测定的pH为12.0〜14.0，进行成核的成核步骤 以25℃为标准; 以及通过将含有在成核步骤中形成的核的颗粒生长用水溶液的pH控制为在液体温度25℃下测定的pH为10.5〜12.0的粒子生长工序。

公开(公告)号：US09954224B2

公开(公告)日：2018-04-24

申请号：US13513244

申请日：2010-12-02

申请人： Hiroyuki Toya ,  Shin Imaizumi ,  Kensaku Mori ,  Atsushi Fukui ,  Kenji Ikeuchi ,  Kazuomi Ryoshi ,  Toshiyuki Osako ,  Hiroki Nagai

发明人： Hiroyuki Toya ,  Shin Imaizumi ,  Kensaku Mori ,  Atsushi Fukui ,  Kenji Ikeuchi ,  Kazuomi Ryoshi ,  Toshiyuki Osako ,  Hiroki Nagai

IPC分类号： H01M4/505 ,  H01M4/525 ,  H01M4/131 ,  C01G53/00 ,  H01M10/052

CPC分类号： H01M4/505 ,  C01G53/00 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/52 ,  C01P2004/61 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/525 ,  H01M10/052 ,  Y02T10/7011

摘要： An object of the present invention is to provide nickel cobalt manganese composite hydroxide particles having a small particle diameter and a uniform particle size distribution, and a method for producing the same.[Solution]A method for producing a nickel cobalt manganese composite hydroxide by a crystallization reaction is provided. The method includes: a nucleation step of performing nucleation by controlling a pH of an aqueous solution for nucleation including metal compounds containing nickel, cobalt and manganese, and an ammonium ion donor to 12.0 to 14.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard; and a particle growth step of growing nuclei by controlling a pH of an aqueous solution for particle growth containing nuclei formed in the nucleation step to 10.5 to 12.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard.

公开(公告)号：US20130078520A1

公开(公告)日：2013-03-28

申请号：US13520915

申请日：2011-08-26

申请人： Hiroyuki Toya ,  Kazuomi Ryoshi ,  Toshiyuki Osako

发明人： Hiroyuki Toya ,  Kazuomi Ryoshi ,  Toshiyuki Osako

IPC分类号： H01M4/52 ,  H01M4/525

CPC分类号： H01M4/485 ,  C01G53/00 ,  C01G53/006 ,  C01G53/50 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2004/32 ,  C01P2004/50 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2004/88 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/362 ,  H01M4/483 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0427 ,  H01M10/052 ,  H01M2004/028 ,  Y02E60/122 ,  Y02P70/54

摘要： Provided are nickel manganese composite hydroxide particles that are a precursor for forming cathode active material comprising lithium nickel manganese composite oxide having hollow structure of particles having a small and uniform particle size for obtaining a non-aqueous electrolyte secondary battery having high capacity, high output and good cyclability.When obtaining the nickel manganese composite hydroxide particles from a crystallization reaction, an aqueous solution for nucleation, which includes at least a metallic compound that contains nickel and a metallic compound that contains manganese, and does not include a complex ion formation agent that forms complex ions with nickel, manganese and cobalt, is controlled so that the temperature of the solution is 60° C. or greater, and so that the pH value that is measured at a standard solution temperature of 25° C. is 11.5 to 13.5, and after nucleation is performed, an aqueous solution for particle growth, which includes the nuclei that were formed in the nucleation step and does not substantially include a complex ion formation agent that forms complex ions with nickel, manganese and cobalt, is controlled so that the temperature of the solution is 60° C. or greater, and so that the pH value that is measured at a standard solution temperature of 25° C. is 9.5 to 11.5, and is less than the pH value in the nucleation step.

公开(公告)号：US08288053B2

公开(公告)日：2012-10-16

申请号：US11990342

申请日：2006-08-10

申请人： Norimichi Yonesato ,  Hiroyuki Toya ,  Kazuomi Ryoshi ,  Tai Ito ,  Shoji Futaki

发明人： Norimichi Yonesato ,  Hiroyuki Toya ,  Kazuomi Ryoshi ,  Tai Ito ,  Shoji Futaki

IPC分类号： H01M4/02 ,  H01B1/02

CPC分类号： C01G53/00 ,  C01P2002/32 ,  C01P2002/52 ,  C01P2004/62 ,  C01P2006/12 ,  C01P2006/32 ,  C01P2006/40 ,  C01P2006/80 ,  H01M4/8652 ,  H01M4/8875 ,  H01M4/8885 ,  H01M4/9016 ,  H01M4/9025 ,  H01M4/9033 ,  H01M2004/8684 ,  H01M2008/1293

摘要： This invention provides a nickel oxide powder material, a production process thereof with high efficiency, a raw material composition for use in the same, and an anode material using the nickel oxide powder material. The nickel oxide powder material, when used as an anode material for a solid oxide fuel cell, can reduce heat shrinkage percentage in calcination to reduce a shrinkage difference from other component, and can suppress the occurrence of cracking, delamination, warpage and the like during calcining. Also in power generation after re-reduction after exposure of the anode once to an oxidizing atmosphere, for example, due to the disruption of the fuel supply, deterioration of microstructure of the anode can be suppressed, and the voltage drop percentage of the cell can be reduced. The nickel oxide powder material is used in an anode material constituting a solid oxide fuel cell and is characterized in that spinel compound represented by compositional formula: NiM2O4 wherein M represents a metal element is formed inside or on the surface of the nickel oxide powder or at the interface between the powder particles.

摘要翻译： 本发明提供一种氧化镍粉末材料，其高效率的制造方法，使用该氧化镍粉末材料的原料组合物和使用该氧化镍粉末材料的负极材料。 当用作固体氧化物燃料电池的负极材料时，氧化镍粉末材料可以降低煅烧时的热收缩率，以减少与其它组分的收缩差异，并且可以抑制在其中发生开裂，分层，翘曲等现象 煅烧 另外，在将阳极曝光一次至氧化气氛后的再还原后的发电中，例如由于燃料供给的破坏，能够抑制阳极的组织的劣化，电池的电压下降百分比 减少 氧化镍粉末材料用于构成固体氧化物燃料电池的负极材料中，其特征在于，其中M表示金属元素的组成式：NiM 2 O 4表示的尖晶石化合物形成在氧化镍粉末的表面内或表面上，或者在 粉末颗粒之间的界面。

公开(公告)号：US20090136812A1

公开(公告)日：2009-05-28

申请号：US11990342

申请日：2006-08-10

申请人： Norimichi Yonesato ,  Hiroyuki Toya ,  Kazuomi Ryoshi ,  Tai Ito ,  Shoji Futaki

发明人： Norimichi Yonesato ,  Hiroyuki Toya ,  Kazuomi Ryoshi ,  Tai Ito ,  Shoji Futaki

IPC分类号： H01M4/02 ,  H01B1/02

CPC分类号： C01G53/00 ,  C01P2002/32 ,  C01P2002/52 ,  C01P2004/62 ,  C01P2006/12 ,  C01P2006/32 ,  C01P2006/40 ,  C01P2006/80 ,  H01M4/8652 ,  H01M4/8875 ,  H01M4/8885 ,  H01M4/9016 ,  H01M4/9025 ,  H01M4/9033 ,  H01M2004/8684 ,  H01M2008/1293

摘要： This invention provides a nickel oxide powder material, a production process thereof with high efficiency, a raw material composition for use in the same, and an anode material using the nickel oxide powder material. The nickel oxide powder material, when used as an anode material for a solid oxide fuel cell, can reduce heat shrinkage percentage in calcination to reduce a shrinkage difference from other component, and can suppress the occurrence of cracking, delamination, warpage and the like during calcining. Also in power generation after re-reduction after exposure of the anode once to an oxidizing atmosphere, for example, due to the disruption of the fuel supply, deterioration of microstructure of the anode can be suppressed, and the voltage drop percentage of the cell can be reduced. The nickel oxide powder material is used in an anode material constituting a solid oxide fuel cell and is characterized in that spinel compound represented by compositional formula: NiM2O4 wherein M represents a metal element is formed inside or on the surface of the nickel oxide powder or at the interface between the powder particles.

摘要翻译： 本发明提供一种氧化镍粉末材料，其高效率的制造方法，使用该氧化镍粉末材料的原料组合物和使用该氧化镍粉末材料的负极材料。 当用作固体氧化物燃料电池的负极材料时，氧化镍粉末材料可以降低煅烧时的热收缩率，以减少与其它组分的收缩差异，并且可以抑制在其中发生开裂，分层，翘曲等现象 煅烧 另外，在将阳极曝光一次至氧化气氛后的再还原后的发电中，例如由于燃料供给的破坏，能够抑制阳极的组织的劣化，电池的电压下降百分比 减少 氧化镍粉末材料用于构成固体氧化物燃料电池的负极材料中，其特征在于，其中M表示金属元素的组成式：NiM 2 O 4表示的尖晶石化合物形成在氧化镍粉末的表面内或表面上，或者在 粉末颗粒之间的界面。

公开(公告)号：US08535573B2

公开(公告)日：2013-09-17

申请号：US12734489

申请日：2008-10-31

申请人： Kazuomi Ryoshi ,  Yasumasa Hattori ,  Hiroko Oshita

发明人： Kazuomi Ryoshi ,  Yasumasa Hattori ,  Hiroko Oshita

IPC分类号： H01B1/02 ,  H01B1/22

CPC分类号： B82Y30/00 ,  B22F1/0022 ,  B22F1/025 ,  B22F9/24 ,  B22F2998/00 ,  B22F2999/00 ,  C22B5/00 ,  C22B15/0084 ,  Y02P10/236 ,  B22F2301/10 ,  B22F2301/25 ,  B22F2304/054

摘要： A method for producing copper fine particles by heating and reducing an oxide, hydroxide, or salt of copper included in a solution of ethylene glycol, diethylene glycol, or triethylene glycol, the method comprising controlling a total halogen content of the solution to be less than 20 ppm by mass relative to copper and adding a water-soluble polymer as a dispersant such as polyethyleneimine and a noble metal compound or noble metal colloid for nucleation to the solution. This method makes it possible to provide copper fine particles for use in a wiring material, which are very fine as small as 50 nm or less in average particle size and high dispersibility, extremely low undesirable halogen content, and can be sintered at a low temperature.

摘要翻译： 通过加热和还原包含在乙二醇，二甘醇或三甘醇的溶液中的铜的氧化物，氢氧化物或盐的铜生产铜微粒的方法，包括将溶液的总卤素含量控制在小于 加入相对于铜的20质量ppm，并加入作为分散剂的水溶性聚合物，例如聚乙烯亚胺和用于成核的贵金属化合物或贵金属胶体。 该方法使得可以提供用于布线材料的铜微粒，其平均粒径小到50nm以下，分散性高，极低的不希望的卤素含量，并且可以在低温下烧结 。

公开(公告)号：US20100230644A1

公开(公告)日：2010-09-16

申请号：US12734489

申请日：2008-10-31

申请人： Kazuomi Ryoshi ,  Yasumasa Hattori ,  Hiroko Oshita

发明人： Kazuomi Ryoshi ,  Yasumasa Hattori ,  Hiroko Oshita

IPC分类号： H01B1/22

CPC分类号： B82Y30/00 ,  B22F1/0022 ,  B22F1/025 ,  B22F9/24 ,  B22F2998/00 ,  B22F2999/00 ,  C22B5/00 ,  C22B15/0084 ,  Y02P10/236 ,  B22F2301/10 ,  B22F2301/25 ,  B22F2304/054

摘要： A method for producing copper fine particles by heating and reducing an oxide, hydroxide, or salt of copper included in a solution of ethylene glycol, diethylene glycol, or triethylene glycol, the method comprising controlling a total halogen content of the solution to be less than 20 ppm by mass relative to copper and adding a water-soluble polymer as a dispersant such as polyethyleneimine and a noble metal compound or noble metal colloid for nucleation to the solution. This method makes it possible to provide copper fine particles for use in a wiring material, which are very fine as small as 50 nm or less in average particle size and high dispersibility, extremely low undesirable halogen content, and can be sintered at a low temperature.

摘要翻译： 通过加热和还原包含在乙二醇，二甘醇或三甘醇的溶液中的铜的氧化物，氢氧化物或盐的铜生产铜微粒的方法，包括将溶液的总卤素含量控制在小于 加入相对于铜的20质量ppm，并加入作为分散剂的水溶性聚合物，例如聚乙烯亚胺和用于成核的贵金属化合物或贵金属胶体。 该方法使得可以提供用于布线材料的铜微粒，其平均粒径小到50nm以下，分散性高，极低的不希望的卤素含量，并且可以在低温下烧结 。