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1.发明申请公开(公告)号：US20120270107A1
公开(公告)日：2012-10-25
申请号：US13513244
申请日：2010-12-02
申请人： Hiroyuki Toya , Shin Imaizumi , Kensaku Mori , Atsushi Fukui , Kenji Ikeuchi , Kazuomi Ryoshi , Toshiyuki Osako , Hiroki Nagai
发明人： Hiroyuki Toya , Shin Imaizumi , Kensaku Mori , Atsushi Fukui , Kenji Ikeuchi , Kazuomi Ryoshi , Toshiyuki Osako , Hiroki Nagai
IPC分类号： H01M4/131
CPC分类号： H01M4/505 , C01G53/00 , C01G53/006 , C01G53/50 , C01P2002/52 , C01P2002/72 , C01P2004/03 , C01P2004/52 , C01P2004/61 , C01P2006/40 , H01M4/131 , H01M4/525 , H01M10/052 , Y02T10/7011
摘要： An object of the present invention is to provide nickel cobalt manganese composite hydroxide particles having a small particle diameter and a uniform particle size distribution, and a method for producing the same.[Solution]A method for producing a nickel cobalt manganese composite hydroxide by a crystallization reaction is provided. The method includes: a nucleation step of performing nucleation by controlling a pH of an aqueous solution for nucleation including metal compounds containing nickel, cobalt and manganese, and an ammonium ion donor to 12.0 to 14.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard; and a particle growth step of growing nuclei by controlling a pH of an aqueous solution for particle growth containing nuclei formed in the nucleation step to 10.5 to 12.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard.
摘要翻译： 本发明的目的是提供具有小粒径和均匀粒度分布的镍钴锰复合氢氧化物颗粒及其制造方法。 [解决方案]提供了通过结晶反应制造镍钴锰复合氢氧化物的方法。 该方法包括：通过将包含镍，钴和锰的金属化合物和铵离子给体的成核水溶液的pH控制在液体温度下测定的pH为12.0〜14.0，进行成核的成核步骤 以25℃为标准; 以及通过将含有在成核步骤中形成的核的颗粒生长用水溶液的pH控制为在液体温度25℃下测定的pH为10.5〜12.0的粒子生长工序。
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公开(公告)号：US09954224B2
公开(公告)日：2018-04-24
申请号：US13513244
申请日：2010-12-02
申请人： Hiroyuki Toya , Shin Imaizumi , Kensaku Mori , Atsushi Fukui , Kenji Ikeuchi , Kazuomi Ryoshi , Toshiyuki Osako , Hiroki Nagai
发明人： Hiroyuki Toya , Shin Imaizumi , Kensaku Mori , Atsushi Fukui , Kenji Ikeuchi , Kazuomi Ryoshi , Toshiyuki Osako , Hiroki Nagai
IPC分类号： H01M4/505 , H01M4/525 , H01M4/131 , C01G53/00 , H01M10/052
CPC分类号： H01M4/505 , C01G53/00 , C01G53/006 , C01G53/50 , C01P2002/52 , C01P2002/72 , C01P2004/03 , C01P2004/52 , C01P2004/61 , C01P2006/40 , H01M4/131 , H01M4/525 , H01M10/052 , Y02T10/7011
摘要： An object of the present invention is to provide nickel cobalt manganese composite hydroxide particles having a small particle diameter and a uniform particle size distribution, and a method for producing the same.[Solution]A method for producing a nickel cobalt manganese composite hydroxide by a crystallization reaction is provided. The method includes: a nucleation step of performing nucleation by controlling a pH of an aqueous solution for nucleation including metal compounds containing nickel, cobalt and manganese, and an ammonium ion donor to 12.0 to 14.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard; and a particle growth step of growing nuclei by controlling a pH of an aqueous solution for particle growth containing nuclei formed in the nucleation step to 10.5 to 12.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard.
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公开(公告)号：US20130078520A1
公开(公告)日：2013-03-28
申请号：US13520915
申请日：2011-08-26
申请人： Hiroyuki Toya , Kazuomi Ryoshi , Toshiyuki Osako
发明人： Hiroyuki Toya , Kazuomi Ryoshi , Toshiyuki Osako
CPC分类号： H01M4/485 , C01G53/00 , C01G53/006 , C01G53/50 , C01P2002/52 , C01P2004/03 , C01P2004/32 , C01P2004/50 , C01P2004/51 , C01P2004/61 , C01P2004/88 , H01M4/131 , H01M4/1391 , H01M4/362 , H01M4/483 , H01M4/505 , H01M4/525 , H01M10/0427 , H01M10/052 , H01M2004/028 , Y02E60/122 , Y02P70/54
摘要： Provided are nickel manganese composite hydroxide particles that are a precursor for forming cathode active material comprising lithium nickel manganese composite oxide having hollow structure of particles having a small and uniform particle size for obtaining a non-aqueous electrolyte secondary battery having high capacity, high output and good cyclability.When obtaining the nickel manganese composite hydroxide particles from a crystallization reaction, an aqueous solution for nucleation, which includes at least a metallic compound that contains nickel and a metallic compound that contains manganese, and does not include a complex ion formation agent that forms complex ions with nickel, manganese and cobalt, is controlled so that the temperature of the solution is 60° C. or greater, and so that the pH value that is measured at a standard solution temperature of 25° C. is 11.5 to 13.5, and after nucleation is performed, an aqueous solution for particle growth, which includes the nuclei that were formed in the nucleation step and does not substantially include a complex ion formation agent that forms complex ions with nickel, manganese and cobalt, is controlled so that the temperature of the solution is 60° C. or greater, and so that the pH value that is measured at a standard solution temperature of 25° C. is 9.5 to 11.5, and is less than the pH value in the nucleation step.
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4.发明授权Nickel oxide powder material for solid oxide fuel cell, production process thereof, raw material composition for use in the same, and anode material using the nickel oxide powder material 有权用于固体氧化物燃料电池的氧化镍粉末材料，其制备方法，用于其的原料组合物和使用氧化镍粉末材料的阳极材料公开(公告)号：US08288053B2
公开(公告)日：2012-10-16
申请号：US11990342
申请日：2006-08-10
申请人： Norimichi Yonesato , Hiroyuki Toya , Kazuomi Ryoshi , Tai Ito , Shoji Futaki
发明人： Norimichi Yonesato , Hiroyuki Toya , Kazuomi Ryoshi , Tai Ito , Shoji Futaki
CPC分类号： C01G53/00 , C01P2002/32 , C01P2002/52 , C01P2004/62 , C01P2006/12 , C01P2006/32 , C01P2006/40 , C01P2006/80 , H01M4/8652 , H01M4/8875 , H01M4/8885 , H01M4/9016 , H01M4/9025 , H01M4/9033 , H01M2004/8684 , H01M2008/1293
摘要： This invention provides a nickel oxide powder material, a production process thereof with high efficiency, a raw material composition for use in the same, and an anode material using the nickel oxide powder material. The nickel oxide powder material, when used as an anode material for a solid oxide fuel cell, can reduce heat shrinkage percentage in calcination to reduce a shrinkage difference from other component, and can suppress the occurrence of cracking, delamination, warpage and the like during calcining. Also in power generation after re-reduction after exposure of the anode once to an oxidizing atmosphere, for example, due to the disruption of the fuel supply, deterioration of microstructure of the anode can be suppressed, and the voltage drop percentage of the cell can be reduced. The nickel oxide powder material is used in an anode material constituting a solid oxide fuel cell and is characterized in that spinel compound represented by compositional formula: NiM2O4 wherein M represents a metal element is formed inside or on the surface of the nickel oxide powder or at the interface between the powder particles.
摘要翻译： 本发明提供一种氧化镍粉末材料，其高效率的制造方法，使用该氧化镍粉末材料的原料组合物和使用该氧化镍粉末材料的负极材料。 当用作固体氧化物燃料电池的负极材料时，氧化镍粉末材料可以降低煅烧时的热收缩率，以减少与其它组分的收缩差异，并且可以抑制在其中发生开裂，分层，翘曲等现象 煅烧 另外，在将阳极曝光一次至氧化气氛后的再还原后的发电中，例如由于燃料供给的破坏，能够抑制阳极的组织的劣化，电池的电压下降百分比 减少 氧化镍粉末材料用于构成固体氧化物燃料电池的负极材料中，其特征在于，其中M表示金属元素的组成式：NiM 2 O 4表示的尖晶石化合物形成在氧化镍粉末的表面内或表面上，或者在 粉末颗粒之间的界面。
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5.发明申请Nickel oxide powder material for solid oxide fuel cell, production process thereof, raw material composition for use in the same, and anode material using the nickel oxide powder material 有权用于固体氧化物燃料电池的氧化镍粉末材料，其制备方法，用于其的原料组合物和使用氧化镍粉末材料的阳极材料公开(公告)号：US20090136812A1
公开(公告)日：2009-05-28
申请号：US11990342
申请日：2006-08-10
申请人： Norimichi Yonesato , Hiroyuki Toya , Kazuomi Ryoshi , Tai Ito , Shoji Futaki
发明人： Norimichi Yonesato , Hiroyuki Toya , Kazuomi Ryoshi , Tai Ito , Shoji Futaki
CPC分类号： C01G53/00 , C01P2002/32 , C01P2002/52 , C01P2004/62 , C01P2006/12 , C01P2006/32 , C01P2006/40 , C01P2006/80 , H01M4/8652 , H01M4/8875 , H01M4/8885 , H01M4/9016 , H01M4/9025 , H01M4/9033 , H01M2004/8684 , H01M2008/1293
摘要： This invention provides a nickel oxide powder material, a production process thereof with high efficiency, a raw material composition for use in the same, and an anode material using the nickel oxide powder material. The nickel oxide powder material, when used as an anode material for a solid oxide fuel cell, can reduce heat shrinkage percentage in calcination to reduce a shrinkage difference from other component, and can suppress the occurrence of cracking, delamination, warpage and the like during calcining. Also in power generation after re-reduction after exposure of the anode once to an oxidizing atmosphere, for example, due to the disruption of the fuel supply, deterioration of microstructure of the anode can be suppressed, and the voltage drop percentage of the cell can be reduced. The nickel oxide powder material is used in an anode material constituting a solid oxide fuel cell and is characterized in that spinel compound represented by compositional formula: NiM2O4 wherein M represents a metal element is formed inside or on the surface of the nickel oxide powder or at the interface between the powder particles.
摘要翻译： 本发明提供一种氧化镍粉末材料，其高效率的制造方法，使用该氧化镍粉末材料的原料组合物和使用该氧化镍粉末材料的负极材料。 当用作固体氧化物燃料电池的负极材料时，氧化镍粉末材料可以降低煅烧时的热收缩率，以减少与其它组分的收缩差异，并且可以抑制在其中发生开裂，分层，翘曲等现象 煅烧 另外，在将阳极曝光一次至氧化气氛后的再还原后的发电中，例如由于燃料供给的破坏，能够抑制阳极的组织的劣化，电池的电压下降百分比 减少 氧化镍粉末材料用于构成固体氧化物燃料电池的负极材料中，其特征在于，其中M表示金属元素的组成式：NiM 2 O 4表示的尖晶石化合物形成在氧化镍粉末的表面内或表面上，或者在 粉末颗粒之间的界面。
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公开(公告)号：US20130302687A1
公开(公告)日：2013-11-14
申请号：US13941253
申请日：2013-07-12
申请人： Hiroki Nagai , Masahiro Morita , Kensaku Mori , Shin Imaizumi , Kenji Ikeuchi , Toshiyuki Osako , Hiroyuki Toya
发明人： Hiroki Nagai , Masahiro Morita , Kensaku Mori , Shin Imaizumi , Kenji Ikeuchi , Toshiyuki Osako , Hiroyuki Toya
CPC分类号： H01M4/366 , C01G53/006 , C01G53/50 , C01P2002/52 , C01P2004/03 , C01P2004/61 , C01P2006/11 , C01P2006/12 , C01P2006/16 , H01M4/131 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M2004/021 , Y02E60/122 , Y02P70/54 , Y02T10/7011
摘要： Active material particles are provided that exhibit performance suitable for increasing the output of a lithium secondary battery and little deterioration due to charge-discharge cycling. The active material particles provided by the present invention have a hollow structure having secondary particles including an aggregate of a plurality of primary particles of a lithium transition metal oxide, and a hollow portion formed inside the secondary particles, and through holes that penetrates to the hollow portion from the outside are formed in the secondary particles. BET specific surface area of the active material particles is 0.5 to 1.9 m2/g.
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公开(公告)号：US20120282525A1
公开(公告)日：2012-11-08
申请号：US13513209
申请日：2010-10-07
申请人： Hiroki Nagai , Masahiro Morita , Kensaku Mori , Shin Imaizumi , Kenji Ikeuchi , Toshiyuki Osako , Hiroyuki Toya
发明人： Hiroki Nagai , Masahiro Morita , Kensaku Mori , Shin Imaizumi , Kenji Ikeuchi , Toshiyuki Osako , Hiroyuki Toya
IPC分类号： H01M4/525
CPC分类号： H01M4/366 , C01G53/006 , C01G53/50 , C01P2002/52 , C01P2004/03 , C01P2004/61 , C01P2006/11 , C01P2006/12 , C01P2006/16 , H01M4/131 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M2004/021 , Y02E60/122 , Y02P70/54 , Y02T10/7011
摘要： Active material particles are provided that exhibit performance suitable for increasing the output of a lithium secondary battery and little deterioration due to charge-discharge cycling. The active material particles provided by the present invention have a hollow structure having secondary particles including an aggregate of a plurality of primary particles of a lithium transition metal oxide, and a hollow portion formed inside the secondary particles, and through holes that penetrates to the hollow portion from the outside are formed in the secondary particles. BET specific surface area of the active material particles is 0.5 to 1.9 m2/g.
摘要翻译： 提供活性物质颗粒，其表现出适合于增加锂二次电池的输出并且由于充放电循环而导致的劣化。 由本发明提供的活性物质颗粒具有中空结构，其具有二次粒子，其具有多个锂过渡金属氧化物的一次粒子的聚集体和形成在二次粒子内部的中空部分，以及穿透到中空部的通孔 从二次颗粒形成从外部的部分。 活性物质粒子的BET比表面积为0.5〜1.9m 2 / g。
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8.发明申请公开(公告)号：US20140011090A1
公开(公告)日：2014-01-09
申请号：US13820110
申请日：2011-03-28
申请人： Hiroyuki Toya , Kensaku Mori , Shin Imaizumi , Kenji Ikeuchi , Toshiyuki Osako
发明人： Hiroyuki Toya , Kensaku Mori , Shin Imaizumi , Kenji Ikeuchi , Toshiyuki Osako
CPC分类号： C30B7/14 , C01G53/006 , C01G53/50 , C01P2002/52 , C01P2004/03 , C01P2004/34 , C01P2004/51 , C01P2004/61 , C01P2004/62 , C01P2006/40 , H01M4/0471 , H01M4/0497 , H01M4/366 , H01M4/505 , H01M4/525 , H01M10/0525 , Y10T428/2982
摘要： Provided are nickel manganese composite hydroxide particles having a small and uniform particle size and having a double structure which enables to obtain a cathode active material having a hollow structure, and a manufacturing method thereof. When obtaining the nickel manganese composite hydroxide by a reaction crystallization, using an aqueous solution for nucleation, which includes at least a metallic compound that contains nickel, a metallic compound that contains manganese and an ammonium ion donor and controlling the pH value that is measured at a standard solution temperature of 25° C. is 10.5 to 12.0, nucleation is performed in an oxidizing atmosphere in which the oxygen concentration is greater than 1% by volume, and then nuclei are grown by switching the atmosphere from the oxidizing atmosphere to a mixed atmosphere of oxygen and inert gas in which the oxygen concentration is 1% by volume or less.
摘要翻译： 提供具有小而均匀的粒度的镍锰复合氢氧化物颗粒及其制造方法，其具有能够获得具有中空结构的正极活性物质的双重结构。 当通过反应结晶获得镍锰复合氢氧化物时，使用包含至少含有镍的金属化合物的成核水溶液，含有锰和铵离子供体的金属化合物，并控制在 25℃的标准溶液温度为10.5〜12.0，在氧浓度大于1体积％的氧化气氛中进行成核，然后通过将氧化气氛的气氛转换为混合 氧浓度为1体积％以下的氧气和惰性气体。
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9.发明授权Method of producing active material particles with lithium transition metal oxide secondary particles 有权用锂过渡金属氧化物二次颗粒生产活性物质颗粒的方法公开(公告)号：US08486564B2
公开(公告)日：2013-07-16
申请号：US13618526
申请日：2012-09-14
申请人： Hiroki Nagai , Masahiro Morita , Kensaku Mori , Shin Imaizumi , Kenji Ikeuchi , Toshiyuki Osako , Hiroyuki Toya
发明人： Hiroki Nagai , Masahiro Morita , Kensaku Mori , Shin Imaizumi , Kenji Ikeuchi , Toshiyuki Osako , Hiroyuki Toya
IPC分类号： H01M4/13
CPC分类号： H01M4/366 , C01G53/006 , C01G53/50 , C01P2002/52 , C01P2004/03 , C01P2004/61 , C01P2006/11 , C01P2006/12 , C01P2006/16 , H01M4/131 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M2004/021 , Y02E60/122 , Y02P70/54 , Y02T10/7011
摘要： Active material particles are provided that exhibit performance suitable for increasing the output of a lithium secondary battery and little deterioration due to charge-discharge cycling. The active material particles provided by the present invention have a hollow structure having secondary particles including an aggregate of a plurality of primary particles of a lithium transition metal oxide, and a hollow portion formed inside the secondary particles, and through holes that penetrates to the hollow portion from the outside are formed in the secondary particles. BET specific surface area of the active material particles is 0.5 to 1.9 m2/g.
摘要翻译： 提供活性物质颗粒，其表现出适合于增加锂二次电池的输出并且由于充放电循环而导致的劣化。 由本发明提供的活性物质颗粒具有中空结构，其具有二次粒子，其具有多个锂过渡金属氧化物的一次粒子的聚集体和形成在二次粒子内部的中空部分，以及穿透到中空部的通孔 从二次颗粒形成从外部的部分。 活性物质粒子的BET比表面积为0.5〜1.9m 2 / g。
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公开(公告)号：US10017875B2
公开(公告)日：2018-07-10
申请号：US13820110
申请日：2011-03-28
申请人： Hiroyuki Toya , Kensaku Mori , Shin Imaizumi , Kenji Ikeuchi , Toshiyuki Osako
发明人： Hiroyuki Toya , Kensaku Mori , Shin Imaizumi , Kenji Ikeuchi , Toshiyuki Osako
CPC分类号： C30B7/14 , C01G53/006 , C01G53/50 , C01P2002/52 , C01P2004/03 , C01P2004/34 , C01P2004/51 , C01P2004/61 , C01P2004/62 , C01P2006/40 , H01M4/0471 , H01M4/0497 , H01M4/366 , H01M4/505 , H01M4/525 , H01M10/0525 , Y10T428/2982
摘要： Provided are nickel manganese composite hydroxide particles having a small and uniform particle size and having a double structure which enables to obtain a cathode active material having a hollow structure, and a manufacturing method thereof. When obtaining the nickel manganese composite hydroxide by a reaction crystallization, using an aqueous solution for nucleation, which includes at least a metallic compound that contains nickel, a metallic compound that contains manganese and an ammonium ion donor and controlling the pH value that is measured at a standard solution temperature of 25° C. is 10.5 to 12.0, nucleation is performed in an oxidizing atmosphere in which the oxygen concentration is greater than 1% by volume, and then nuclei are grown by switching the atmosphere from the oxidizing atmosphere to a mixed atmosphere of oxygen and inert gas in which the oxygen concentration is 1% by volume or less.
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