A dye-sensitized solar cell includes: a collective electrode having a light-transmitting function, a photoelectrode to be electrically connected to the collective electrode and being a semiconductor layer having a dye adsorbed thereon, and a counter electrode apart from the photoelectrode arranged in the interior of a tube-shaped vessel formed of a transparent glass; glass sealed portions formed at both ends of the tube-shaped vessel; external leads penetrating through the glass sealed portions and drawn out of the tube-shaped vessel; and an electrolytic solution filled in the tube-shaped vessel and hermetically sealed wherein the counter electrode includes an electric double-layer capacitor, the electric double-layer capacitor includes the counter electrode which also serves as a positive polarized electrode, a negative polarized electrode arranged apart therefrom inside of the counter electrode, and a separator arranged between the counter electrode and the negative polarized electrode, and the electrolytic solution filled therein.