发明申请
- 专利标题: PHOSPHORUS-CONTAINING ULTRASTABLE Y-TYPE RARE EARTH MOLECULAR SIEVE AND PREPARATION METHOD THEREFOR
- 专利标题(中): 含磷的超可控Y型稀土分子筛及其制备方法
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申请号: US14404774申请日: 2012-07-27
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公开(公告)号: US20150209767A1公开(公告)日: 2015-07-30
- 发明人: Xionghou Gao , Haitao Zhang , Di Li , Xueli Li , Hongchang Duan , Zhengguo Tan , Chaowei Liu , Yunfeng Zheng , Xiaoliang Huang , Jinjun Cai , Chenxi Zhang , Zhishuang Pan , Gengzhen Cao
- 申请人: Xionghou Gao , Haitao Zhang , Di Li , Xueli Li , Hongchang Duan , Zhengguo Tan , Chaowei Liu , Yunfeng Zheng , Xiaoliang Huang , Jinjun Cai , Chenxi Zhang , Zhishuang Pan , Gengzhen Cao
- 申请人地址: CN Beijing
- 专利权人: PetroChina Company Limited
- 当前专利权人: PetroChina Company Limited
- 当前专利权人地址: CN Beijing
- 优先权: CN201210179835.9 20120601
- 国际申请: PCT/CN2012/001007 WO 20120727
- 主分类号: B01J29/08
- IPC分类号: B01J29/08 ; B01J37/00 ; B01J37/06 ; B01J37/04 ; C01B39/24 ; B01J37/08
摘要:
Provided is a phosphorus-containing ultrastable Y-type rare earth (RE) molecular sieve and the preparation method thereof. The method is: based on Na Y molecular sieve as a raw material, obtaining “one-exchange one-roast” RE-Na Y-type molecular sieve through the steps of exchanging with RE, pre-exchanging with dispersing, and the first calcination; and then performing ammonium salt exchange, phosphorus modification, and the second calcination on the “one-exchange one-roast” RE-Na Y-type molecular sieve, wherein the sequence of the RE exchange and the pre-exchange with dispersing is unlimited, and the sequence of the ammonium salt exchange and the phosphorus modification is unlimited as well. The obtained molecular sieve contains RE oxide 1-20 wt %, phosphorus 0.1-5 wt %, and sodium oxide no more than 1.2 wt %, and has a crystallization degree of 51-69% and a lattice parameter of 2.449-2.469 nm. Heavy oil conversion rate can be increased by using the molecular sieve as an active component in a catalytic cracking catalyst.
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