Invention Application
US20150311512A1 Bimodal Lithium Transition Metal Based Oxide Powder for Use in a Rechargeable Battery
审中-公开
用于充电电池的双峰型锂转移金属氧化物粉末
- Patent Title: Bimodal Lithium Transition Metal Based Oxide Powder for Use in a Rechargeable Battery
- Patent Title (中): 用于充电电池的双峰型锂转移金属氧化物粉末
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Application No.: US14650974Application Date: 2013-11-28
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Publication No.: US20150311512A1Publication Date: 2015-10-29
- Inventor: Jens PAULSEN , Hye Yun YANG
- Applicant: UMICORE , UMICORE KOREA LTD.
- Priority: EP12197350.7 20121214
- International Application: PCT/EP2013/074961 WO 20131128
- Main IPC: H01M4/36
- IPC: H01M4/36 ; H01M4/54 ; H01M4/525 ; H01M4/485 ; H01M4/505

Abstract:
A bimodal lithium transition metal oxide based powder for a rechargeable battery, comprising: a first lithium transition metal oxide based powder, either comprising a material having a layered crystal structure consisting of the elements Li, a metal M and oxygen, wherein the Li content is stoichiometrically controlled, wherein the metal M has the formula M=Co1-a M′a, with 0≦a≦0.05, and wherein M′ is either one or more metals of the group consisting of Al, Ga and B; or comprising a core material and a surface layer, the core having a layered crystal structure consisting of the elements Li, a metal M and oxygen, wherein the Li content is stoichiometrically controlled, wherein the metal M has the formula M=Co1-a M′a, with 0≦a≦0.05, wherein M′ is either one or more metals of the group consisting of Al, Ga and B; and the surface layer consisting of a mixture of the elements of the core material and inorganic N-based oxides, wherein N is either one or more metals of the group consisting of Mg, Ti, Fe, Cu, Ca, Ba, Y, Sn, Sb, Na, Zn, Zr, Si, Nb, Mo, Ru, Rh, Pd, Ag, Cd, Sc, Ce, Pr, Nd, Gd, Dy, and Er; the first powder having an average particle size (D50) of at least 15 μm; and a second lithium transition metal oxide based powder having the formula Li1+bN′1−bO2, wherein 0.10≦b≦0.25, and N′═NixMnyCozAd, wherein 0.10≦x≦0.60, 0.30≦y≦0.80, 0.05≦z≦0.20 and 0≦d≦0.10, A being a dopant, the second powder having an average particle size (D50) of less than 5 μm, and preferably less than 2 μm.
Public/Granted literature
- US10069140B2 Bimodal lithium transition metal based oxide powder for use in a rechargeable battery Public/Granted day:2018-09-04
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