An X-ray apparatus includes an X-ray source configured to radiate X-rays onto an object, an X-ray detector configured to detect X-rays having penetrated through the object among the radiated X-rays and obtain pieces of raw data of different energy bands based on the detected X-rays, a raw image obtainer configured to obtain raw images in which different materials constituting the object are enhanced using the pieces of raw data, and an image processor configured to process the raw images and generate an X-ray image of the object based on the processed raw images.