Disclosed is a largescale nanofiber electrode array using aligned metal nanofiber, which includes preparing a metal precursor/organic polymer complex solution, forming an aligned metal/polymer complex nanofiber pattern with a continuously connected shape on a substrate to by injecting the solution with an electric field aided robotic nozzle printer and moving the substrate, and performing thermal treatment on the complex nanofiber pattern to form an aligned nanofiber metal pattern. Accordingly, the position and direction of the metal nanofiber pattern can be accurately controlled, and the metal nanofiber pattern can be aligned in a desired direction.